Crystal structure of TiBi(2)

Black granular single crystals of monotitanium dibismuth, TiBi(2), were synthesized by slow cooling of a mixture of Bi and Ti from 693 K. The title compound is isostructural with CuMg(2) (ortho­rhom­bic Fddd symmetry). Ti atoms are located in square anti­prisms of Bi atoms. The network of one type o...

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Detalles Bibliográficos
Autores principales: Watanabe, Kei, Yamane, Hisanori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120700/
https://www.ncbi.nlm.nih.gov/pubmed/27920910
http://dx.doi.org/10.1107/S2056989016012391
Descripción
Sumario:Black granular single crystals of monotitanium dibismuth, TiBi(2), were synthesized by slow cooling of a mixture of Bi and Ti from 693 K. The title compound is isostructural with CuMg(2) (ortho­rhom­bic Fddd symmetry). Ti atoms are located in square anti­prisms of Bi atoms. The network of one type of Bi atom spirals along the a-axis direction while honeycomb layers of the other type of Bi atom spreading in the ab plane inter­lace one another.

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