Crystal structure of 4-[4-(eth­oxy­carbon­yl)piperazin-1-yl]benzoic acid

The asymmetric unit of the title compound, C(14)H(18)N(2)O(4), contains two independent mol­ecules (A and B) which have essentially the same conformation. The piperazine rings adopts chair conformations with the N atoms out of plane. The dihedral angles formed by the four approximately planar C atom...

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Autores principales: Faizi, Md. Serajul Haque, Ahmad, Musheer, Golenya, Irina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120704/
https://www.ncbi.nlm.nih.gov/pubmed/27920914
http://dx.doi.org/10.1107/S2056989016012482
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author Faizi, Md. Serajul Haque
Ahmad, Musheer
Golenya, Irina A.
author_facet Faizi, Md. Serajul Haque
Ahmad, Musheer
Golenya, Irina A.
author_sort Faizi, Md. Serajul Haque
collection PubMed
description The asymmetric unit of the title compound, C(14)H(18)N(2)O(4), contains two independent mol­ecules (A and B) which have essentially the same conformation. The piperazine rings adopts chair conformations with the N atoms out of plane. The dihedral angles formed by the four approximately planar C atoms of the piperazine ring and the benzene ring is 30.8 (5)° in mol­ecule A and 30.6 (5)° in mol­ecule B. In the crystal, mol­ecules A and B are connected by a pair of O—H⋯O hydrogen bonds, forming a dimer with graph-set notation R (2) (2)(8). Weak C—H⋯O hydrogen bonds connect the dimers, forming zigzag chains along [001].
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spelling pubmed-51207042016-12-05 Crystal structure of 4-[4-(eth­oxy­carbon­yl)piperazin-1-yl]benzoic acid Faizi, Md. Serajul Haque Ahmad, Musheer Golenya, Irina A. Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, C(14)H(18)N(2)O(4), contains two independent mol­ecules (A and B) which have essentially the same conformation. The piperazine rings adopts chair conformations with the N atoms out of plane. The dihedral angles formed by the four approximately planar C atoms of the piperazine ring and the benzene ring is 30.8 (5)° in mol­ecule A and 30.6 (5)° in mol­ecule B. In the crystal, mol­ecules A and B are connected by a pair of O—H⋯O hydrogen bonds, forming a dimer with graph-set notation R (2) (2)(8). Weak C—H⋯O hydrogen bonds connect the dimers, forming zigzag chains along [001]. International Union of Crystallography 2016-08-09 /pmc/articles/PMC5120704/ /pubmed/27920914 http://dx.doi.org/10.1107/S2056989016012482 Text en © Faizi et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Faizi, Md. Serajul Haque
Ahmad, Musheer
Golenya, Irina A.
Crystal structure of 4-[4-(eth­oxy­carbon­yl)piperazin-1-yl]benzoic acid
title Crystal structure of 4-[4-(eth­oxy­carbon­yl)piperazin-1-yl]benzoic acid
title_full Crystal structure of 4-[4-(eth­oxy­carbon­yl)piperazin-1-yl]benzoic acid
title_fullStr Crystal structure of 4-[4-(eth­oxy­carbon­yl)piperazin-1-yl]benzoic acid
title_full_unstemmed Crystal structure of 4-[4-(eth­oxy­carbon­yl)piperazin-1-yl]benzoic acid
title_short Crystal structure of 4-[4-(eth­oxy­carbon­yl)piperazin-1-yl]benzoic acid
title_sort crystal structure of 4-[4-(eth­oxy­carbon­yl)piperazin-1-yl]benzoic acid
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120704/
https://www.ncbi.nlm.nih.gov/pubmed/27920914
http://dx.doi.org/10.1107/S2056989016012482
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