Synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(I)

The title compound, [ReCl(pyAm)(CO)(3)], where pyAm is 1-[(pyridin-2-yl­methyl­idene)amino]­adamantane (C(16)H(20)N(2)), was synthesized from the reaction of [ReCl(CO)(5)] and pyAm in an equimolar ratio. The Re(I) atom resides in an octa­hedral C(3)ClN(2) coordination sphere. The Re—C bond trans to...

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Detalles Bibliográficos
Autores principales: Jimenez, Jorge, Chakraborty, Indranil, Mascharak, Pradip
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120706/
https://www.ncbi.nlm.nih.gov/pubmed/27920916
http://dx.doi.org/10.1107/S205698901601255X
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author Jimenez, Jorge
Chakraborty, Indranil
Mascharak, Pradip
author_facet Jimenez, Jorge
Chakraborty, Indranil
Mascharak, Pradip
author_sort Jimenez, Jorge
collection PubMed
description The title compound, [ReCl(pyAm)(CO)(3)], where pyAm is 1-[(pyridin-2-yl­methyl­idene)amino]­adamantane (C(16)H(20)N(2)), was synthesized from the reaction of [ReCl(CO)(5)] and pyAm in an equimolar ratio. The Re(I) atom resides in an octa­hedral C(3)ClN(2) coordination sphere. The Re—C bond trans to the chloride ligand is noticeably longer compared to the other two Re—C distances. Weak C—H⋯Cl hydrogen-bonding inter­actions consoldiate the packing of the mol­ecules. In this design, the pyAm ligand was employed due to its well-known pharmacokinetic properties.
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spelling pubmed-51207062016-12-05 Synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(I) Jimenez, Jorge Chakraborty, Indranil Mascharak, Pradip Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [ReCl(pyAm)(CO)(3)], where pyAm is 1-[(pyridin-2-yl­methyl­idene)amino]­adamantane (C(16)H(20)N(2)), was synthesized from the reaction of [ReCl(CO)(5)] and pyAm in an equimolar ratio. The Re(I) atom resides in an octa­hedral C(3)ClN(2) coordination sphere. The Re—C bond trans to the chloride ligand is noticeably longer compared to the other two Re—C distances. Weak C—H⋯Cl hydrogen-bonding inter­actions consoldiate the packing of the mol­ecules. In this design, the pyAm ligand was employed due to its well-known pharmacokinetic properties. International Union of Crystallography 2016-08-09 /pmc/articles/PMC5120706/ /pubmed/27920916 http://dx.doi.org/10.1107/S205698901601255X Text en © Jimenez et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Jimenez, Jorge
Chakraborty, Indranil
Mascharak, Pradip
Synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(I)
title Synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(I)
title_full Synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(I)
title_fullStr Synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(I)
title_full_unstemmed Synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(I)
title_short Synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(I)
title_sort synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(i)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120706/
https://www.ncbi.nlm.nih.gov/pubmed/27920916
http://dx.doi.org/10.1107/S205698901601255X
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