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Synthesis and crystal structure of tricarbonylchlorido{1-[(pyridin-2-ylmethylidene)amino]adamantane}rhenium(I)
The title compound, [ReCl(pyAm)(CO)(3)], where pyAm is 1-[(pyridin-2-ylmethylidene)amino]adamantane (C(16)H(20)N(2)), was synthesized from the reaction of [ReCl(CO)(5)] and pyAm in an equimolar ratio. The Re(I) atom resides in an octahedral C(3)ClN(2) coordination sphere. The Re—C bond trans to...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120706/ https://www.ncbi.nlm.nih.gov/pubmed/27920916 http://dx.doi.org/10.1107/S205698901601255X |