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Synthesis and crystal structure of tri­carbonyl­chlorido­{1-[(pyridin-2-yl­methyl­idene)amino]­adamantane}rhenium(I)

The title compound, [ReCl(pyAm)(CO)(3)], where pyAm is 1-[(pyridin-2-yl­methyl­idene)amino]­adamantane (C(16)H(20)N(2)), was synthesized from the reaction of [ReCl(CO)(5)] and pyAm in an equimolar ratio. The Re(I) atom resides in an octa­hedral C(3)ClN(2) coordination sphere. The Re—C bond trans to...

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Detalles Bibliográficos
Autores principales: Jimenez, Jorge, Chakraborty, Indranil, Mascharak, Pradip
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120706/
https://www.ncbi.nlm.nih.gov/pubmed/27920916
http://dx.doi.org/10.1107/S205698901601255X