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A two-dimensional Cd(II) coordination polymer: poly[di­aqua­[μ(3)-5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carboxyl­ato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium]

The reaction of 5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carb­oxy­lic acid with cadmium dichloride leads to the formation of the title two-dimensional coordination polymer, [Cd(C(16)H(8)N(4)O(4))(H(2)O)(2)](n). The metal atom is sevenfold coordinated by one pyrazine and one pyridine N atom, two water O...

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Autores principales: Alfonso, Monserrat, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120711/
https://www.ncbi.nlm.nih.gov/pubmed/27920921
http://dx.doi.org/10.1107/S2056989016012858
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author Alfonso, Monserrat
Stoeckli-Evans, Helen
author_facet Alfonso, Monserrat
Stoeckli-Evans, Helen
author_sort Alfonso, Monserrat
collection PubMed
description The reaction of 5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carb­oxy­lic acid with cadmium dichloride leads to the formation of the title two-dimensional coordination polymer, [Cd(C(16)H(8)N(4)O(4))(H(2)O)(2)](n). The metal atom is sevenfold coordinated by one pyrazine and one pyridine N atom, two water O atoms, and by two carboxyl­ate O atoms, one of which bridges two Cd(II) atoms to form a Cd(2)O(2) unit situated about a centre of inversion. Hence, the ligand coordinates to the cadmium atom in an N,N′,O-tridentate and an O-monodentate manner. Within the polymer network, there are a number of O—H⋯O hydrogen bonds present, involving the water mol­ecules and the carboxyl­ate O atoms. There are also C—H⋯N and C—H⋯O hydrogen bonds present. In the crystal, the polymer networks lie parallel to the bc plane. They are aligned back-to-back along the a axis with the non-coordinating pyridine rings directed into the space between the networks.
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spelling pubmed-51207112016-12-05 A two-dimensional Cd(II) coordination polymer: poly[di­aqua­[μ(3)-5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carboxyl­ato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium] Alfonso, Monserrat Stoeckli-Evans, Helen Acta Crystallogr E Crystallogr Commun Research Communications The reaction of 5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carb­oxy­lic acid with cadmium dichloride leads to the formation of the title two-dimensional coordination polymer, [Cd(C(16)H(8)N(4)O(4))(H(2)O)(2)](n). The metal atom is sevenfold coordinated by one pyrazine and one pyridine N atom, two water O atoms, and by two carboxyl­ate O atoms, one of which bridges two Cd(II) atoms to form a Cd(2)O(2) unit situated about a centre of inversion. Hence, the ligand coordinates to the cadmium atom in an N,N′,O-tridentate and an O-monodentate manner. Within the polymer network, there are a number of O—H⋯O hydrogen bonds present, involving the water mol­ecules and the carboxyl­ate O atoms. There are also C—H⋯N and C—H⋯O hydrogen bonds present. In the crystal, the polymer networks lie parallel to the bc plane. They are aligned back-to-back along the a axis with the non-coordinating pyridine rings directed into the space between the networks. International Union of Crystallography 2016-08-16 /pmc/articles/PMC5120711/ /pubmed/27920921 http://dx.doi.org/10.1107/S2056989016012858 Text en © Alfonso and Stoeckli-Evans 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Alfonso, Monserrat
Stoeckli-Evans, Helen
A two-dimensional Cd(II) coordination polymer: poly[di­aqua­[μ(3)-5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carboxyl­ato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium]
title A two-dimensional Cd(II) coordination polymer: poly[di­aqua­[μ(3)-5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carboxyl­ato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium]
title_full A two-dimensional Cd(II) coordination polymer: poly[di­aqua­[μ(3)-5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carboxyl­ato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium]
title_fullStr A two-dimensional Cd(II) coordination polymer: poly[di­aqua­[μ(3)-5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carboxyl­ato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium]
title_full_unstemmed A two-dimensional Cd(II) coordination polymer: poly[di­aqua­[μ(3)-5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carboxyl­ato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium]
title_short A two-dimensional Cd(II) coordination polymer: poly[di­aqua­[μ(3)-5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carboxyl­ato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium]
title_sort two-dimensional cd(ii) coordination polymer: poly[di­aqua­[μ(3)-5,6-bis­(pyridin-2-yl)pyrazine-2,3-di­carboxyl­ato-κ(5) o (2):o (3):o (3),n (4),n (5)]cadmium]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120711/
https://www.ncbi.nlm.nih.gov/pubmed/27920921
http://dx.doi.org/10.1107/S2056989016012858
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