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A two-dimensional Cd(II) coordination polymer: poly[diaqua[μ(3)-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium]
The reaction of 5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylic acid with cadmium dichloride leads to the formation of the title two-dimensional coordination polymer, [Cd(C(16)H(8)N(4)O(4))(H(2)O)(2)](n). The metal atom is sevenfold coordinated by one pyrazine and one pyridine N atom, two water O...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120711/ https://www.ncbi.nlm.nih.gov/pubmed/27920921 http://dx.doi.org/10.1107/S2056989016012858 |
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author | Alfonso, Monserrat Stoeckli-Evans, Helen |
author_facet | Alfonso, Monserrat Stoeckli-Evans, Helen |
author_sort | Alfonso, Monserrat |
collection | PubMed |
description | The reaction of 5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylic acid with cadmium dichloride leads to the formation of the title two-dimensional coordination polymer, [Cd(C(16)H(8)N(4)O(4))(H(2)O)(2)](n). The metal atom is sevenfold coordinated by one pyrazine and one pyridine N atom, two water O atoms, and by two carboxylate O atoms, one of which bridges two Cd(II) atoms to form a Cd(2)O(2) unit situated about a centre of inversion. Hence, the ligand coordinates to the cadmium atom in an N,N′,O-tridentate and an O-monodentate manner. Within the polymer network, there are a number of O—H⋯O hydrogen bonds present, involving the water molecules and the carboxylate O atoms. There are also C—H⋯N and C—H⋯O hydrogen bonds present. In the crystal, the polymer networks lie parallel to the bc plane. They are aligned back-to-back along the a axis with the non-coordinating pyridine rings directed into the space between the networks. |
format | Online Article Text |
id | pubmed-5120711 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-51207112016-12-05 A two-dimensional Cd(II) coordination polymer: poly[diaqua[μ(3)-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium] Alfonso, Monserrat Stoeckli-Evans, Helen Acta Crystallogr E Crystallogr Commun Research Communications The reaction of 5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylic acid with cadmium dichloride leads to the formation of the title two-dimensional coordination polymer, [Cd(C(16)H(8)N(4)O(4))(H(2)O)(2)](n). The metal atom is sevenfold coordinated by one pyrazine and one pyridine N atom, two water O atoms, and by two carboxylate O atoms, one of which bridges two Cd(II) atoms to form a Cd(2)O(2) unit situated about a centre of inversion. Hence, the ligand coordinates to the cadmium atom in an N,N′,O-tridentate and an O-monodentate manner. Within the polymer network, there are a number of O—H⋯O hydrogen bonds present, involving the water molecules and the carboxylate O atoms. There are also C—H⋯N and C—H⋯O hydrogen bonds present. In the crystal, the polymer networks lie parallel to the bc plane. They are aligned back-to-back along the a axis with the non-coordinating pyridine rings directed into the space between the networks. International Union of Crystallography 2016-08-16 /pmc/articles/PMC5120711/ /pubmed/27920921 http://dx.doi.org/10.1107/S2056989016012858 Text en © Alfonso and Stoeckli-Evans 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Alfonso, Monserrat Stoeckli-Evans, Helen A two-dimensional Cd(II) coordination polymer: poly[diaqua[μ(3)-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ(5) O (2):O (3):O (3),N (4),N (5)]cadmium] |
title | A two-dimensional Cd(II) coordination polymer: poly[diaqua[μ(3)-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ(5)
O
(2):O
(3):O
(3),N
(4),N
(5)]cadmium] |
title_full | A two-dimensional Cd(II) coordination polymer: poly[diaqua[μ(3)-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ(5)
O
(2):O
(3):O
(3),N
(4),N
(5)]cadmium] |
title_fullStr | A two-dimensional Cd(II) coordination polymer: poly[diaqua[μ(3)-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ(5)
O
(2):O
(3):O
(3),N
(4),N
(5)]cadmium] |
title_full_unstemmed | A two-dimensional Cd(II) coordination polymer: poly[diaqua[μ(3)-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ(5)
O
(2):O
(3):O
(3),N
(4),N
(5)]cadmium] |
title_short | A two-dimensional Cd(II) coordination polymer: poly[diaqua[μ(3)-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ(5)
O
(2):O
(3):O
(3),N
(4),N
(5)]cadmium] |
title_sort | two-dimensional cd(ii) coordination polymer: poly[diaqua[μ(3)-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ(5)
o
(2):o
(3):o
(3),n
(4),n
(5)]cadmium] |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120711/ https://www.ncbi.nlm.nih.gov/pubmed/27920921 http://dx.doi.org/10.1107/S2056989016012858 |
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