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Crystal structure of bis­(η(2)-ethyl­ene)(η(5)-penta­methyl­cyclo­penta­dien­yl)cobalt

The title compound, [Co(C(10)H(15))(C(2)H(4))(2)], was prepared by Na/Hg reduction of [Co(2)(C(10)H(15))(2)(μ-Cl)(2)] in THF under an ethyl­ene atmosphere and crystallized from pentane at 193 K. The Co—C(olefin) bonds have an average length of 2.022 (2) Å, while the Co—C(penta­dien­yl) bonds average...

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Detalles Bibliográficos
Autores principales: Ramful, Chandika D., Robertson, Katherine N., Ylijoki, Kai E. O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120712/
https://www.ncbi.nlm.nih.gov/pubmed/27920922
http://dx.doi.org/10.1107/S2056989016012822
Descripción
Sumario:The title compound, [Co(C(10)H(15))(C(2)H(4))(2)], was prepared by Na/Hg reduction of [Co(2)(C(10)H(15))(2)(μ-Cl)(2)] in THF under an ethyl­ene atmosphere and crystallized from pentane at 193 K. The Co—C(olefin) bonds have an average length of 2.022 (2) Å, while the Co—C(penta­dien­yl) bonds average 2.103 (19) Å. The olefin C=C bonds are 1.410 (1) Å. The dihedral angle between the planes defined by the cyclo­penta­dienyl ligand and the two olefin ligands is 0.25 (12)°. In the crystal, mol­ecules are linked into chains by C—H⋯π inter­actions.