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Crystal structures of ethyl {2-[4-(4-isopropylphenyl)thiazol-2-yl]phenyl}carbamate and ethyl {2-[4-(3-nitrophenyl)thiazol-2-yl]phenyl}carbamate
The title compounds, C(21)H(22)N(2)O(2)S (I) and C(18)H(15)N(3)O(4)S (II), are structural analogs of the alkaloid Thiosporine B. Both molecules adopt a near-planar V-shaped conformation, which is consolidated by intramolecular N—H⋯N and C—H⋯O hydrogen bonds. The crystal structure of (I) consists...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120716/ https://www.ncbi.nlm.nih.gov/pubmed/27920926 http://dx.doi.org/10.1107/S2056989016013104 |
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| author | Sukhonosova, Elena V. Sokov, Sergey A. Ostapenko, Gennady I. Bunev, Alexander S. Dorovatovskii, Pavel V. Zubavichus, Yan V. Khrustalev, Victor N. |
| author_facet | Sukhonosova, Elena V. Sokov, Sergey A. Ostapenko, Gennady I. Bunev, Alexander S. Dorovatovskii, Pavel V. Zubavichus, Yan V. Khrustalev, Victor N. |
| author_sort | Sukhonosova, Elena V. |
| collection | PubMed |
| description | The title compounds, C(21)H(22)N(2)O(2)S (I) and C(18)H(15)N(3)O(4)S (II), are structural analogs of the alkaloid Thiosporine B. Both molecules adopt a near-planar V-shaped conformation, which is consolidated by intramolecular N—H⋯N and C—H⋯O hydrogen bonds. The crystal structure of (I) consists of mlecular stacks along the a axis, in which the molecules are linked to each other by π(S)⋯π(C) interactions. In the crystal of (II), molecules are linked into chains by C—H⋯O hydrogen bonds and the chains are cross-linked into (100) sheets by π–π stacking interactions. |
| format | Online Article Text |
| id | pubmed-5120716 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-51207162016-12-05 Crystal structures of ethyl {2-[4-(4-isopropylphenyl)thiazol-2-yl]phenyl}carbamate and ethyl {2-[4-(3-nitrophenyl)thiazol-2-yl]phenyl}carbamate Sukhonosova, Elena V. Sokov, Sergey A. Ostapenko, Gennady I. Bunev, Alexander S. Dorovatovskii, Pavel V. Zubavichus, Yan V. Khrustalev, Victor N. Acta Crystallogr E Crystallogr Commun Research Communications The title compounds, C(21)H(22)N(2)O(2)S (I) and C(18)H(15)N(3)O(4)S (II), are structural analogs of the alkaloid Thiosporine B. Both molecules adopt a near-planar V-shaped conformation, which is consolidated by intramolecular N—H⋯N and C—H⋯O hydrogen bonds. The crystal structure of (I) consists of mlecular stacks along the a axis, in which the molecules are linked to each other by π(S)⋯π(C) interactions. In the crystal of (II), molecules are linked into chains by C—H⋯O hydrogen bonds and the chains are cross-linked into (100) sheets by π–π stacking interactions. International Union of Crystallography 2016-08-19 /pmc/articles/PMC5120716/ /pubmed/27920926 http://dx.doi.org/10.1107/S2056989016013104 Text en © Sukhonosova et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| spellingShingle | Research Communications Sukhonosova, Elena V. Sokov, Sergey A. Ostapenko, Gennady I. Bunev, Alexander S. Dorovatovskii, Pavel V. Zubavichus, Yan V. Khrustalev, Victor N. Crystal structures of ethyl {2-[4-(4-isopropylphenyl)thiazol-2-yl]phenyl}carbamate and ethyl {2-[4-(3-nitrophenyl)thiazol-2-yl]phenyl}carbamate |
| title | Crystal structures of ethyl {2-[4-(4-isopropylphenyl)thiazol-2-yl]phenyl}carbamate and ethyl {2-[4-(3-nitrophenyl)thiazol-2-yl]phenyl}carbamate |
| title_full | Crystal structures of ethyl {2-[4-(4-isopropylphenyl)thiazol-2-yl]phenyl}carbamate and ethyl {2-[4-(3-nitrophenyl)thiazol-2-yl]phenyl}carbamate |
| title_fullStr | Crystal structures of ethyl {2-[4-(4-isopropylphenyl)thiazol-2-yl]phenyl}carbamate and ethyl {2-[4-(3-nitrophenyl)thiazol-2-yl]phenyl}carbamate |
| title_full_unstemmed | Crystal structures of ethyl {2-[4-(4-isopropylphenyl)thiazol-2-yl]phenyl}carbamate and ethyl {2-[4-(3-nitrophenyl)thiazol-2-yl]phenyl}carbamate |
| title_short | Crystal structures of ethyl {2-[4-(4-isopropylphenyl)thiazol-2-yl]phenyl}carbamate and ethyl {2-[4-(3-nitrophenyl)thiazol-2-yl]phenyl}carbamate |
| title_sort | crystal structures of ethyl {2-[4-(4-isopropylphenyl)thiazol-2-yl]phenyl}carbamate and ethyl {2-[4-(3-nitrophenyl)thiazol-2-yl]phenyl}carbamate |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120716/ https://www.ncbi.nlm.nih.gov/pubmed/27920926 http://dx.doi.org/10.1107/S2056989016013104 |
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