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Extending the Study of the 6,8 Rearrangement in Flavylium Compounds to Higher pH Values: Interconversion between 6‐Bromo and 8‐Bromo‐apigeninidin
The rearrangement between isomers 6‐ and 8‐bromo‐apigeninidin (6 and 8) was studied by pH jumps using stopped flow, UV/Vis, NMR, and HPLC analysis. The system constitutes a pH‐dependent network of chemical reactions involving up to 18 different species. The dynamic network is equivalent to a single...
Autores principales: | Cruz, Luís M., Basílio, Nuno M., de Freitas, Victor A., Lima, João C., Pina, Fernando J. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5126205/ https://www.ncbi.nlm.nih.gov/pubmed/27933227 http://dx.doi.org/10.1002/open.201500210 |
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