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Catalytic Asymmetric Allylboration of Indoles and Dihydroisoquinolines with Allylboronic Acids: Stereodivergent Synthesis of up to Three Contiguous Stereocenters

The catalytic asymmetric allylboration of cyclic imines with γ,γ‐disubstituted allylboronic acids provides products with adjacent stereocenters in high yield and stereoselectivity. Various electrophiles, including 3,4‐dihydroisoquinolines and indoles, were prenylated in a fully stereodivergent fashi...

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Detalles Bibliográficos
Autores principales: Alam, Rauful, Diner, Colin, Jonker, Sybrand, Eriksson, Lars, Szabó, Kálmán J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5129484/
https://www.ncbi.nlm.nih.gov/pubmed/27735124
http://dx.doi.org/10.1002/anie.201608605

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