Cargando…

Enantioselective Stereodivergent Nucleophile‐Dependent Isothiourea‐Catalysed Domino Reactions

α,β‐Unsaturated acyl ammoniums generated from the reaction of α,β‐unsaturated 2,4,6‐trichlorophenol (TCP) esters bearing a pendent enone with an isothiourea organocatalyst are versatile intermediates in a range of enantioselective nucleophile‐dependent domino processes to form complex products of di...

Descripción completa

Detalles Bibliográficos
Autores principales:	Matviitsuk, Anastassia, Taylor, James E., Cordes, David B., Slawin, Alexandra M. Z., Smith, Andrew D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2016
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5132085/ https://www.ncbi.nlm.nih.gov/pubmed/27727506 http://dx.doi.org/10.1002/chem.201603318

Ejemplares similares

Enantioselective isothiourea-catalysed reversible Michael addition of aryl esters to 2-benzylidene malononitriles
por: Nimmo, Alastair J., et al.
Publicado: (2023)

Isothiourea-catalysed enantioselective pyrrolizine synthesis: synthetic and computational studies
por: Stark, Daniel G., et al.
Publicado: (2016)

Asymmetric Isothiourea-Catalysed Formal [3+2] Cycloadditions of Ammonium Enolates with Oxaziridines
por: Smith, Siobhan R, et al.
Publicado: (2015)

Enantioselective Synthesis of 3,5,6‐Substituted Dihydropyranones and Dihydropyridinones using Isothiourea‐Mediated Catalysis
por: Stark, Daniel G., et al.
Publicado: (2015)

Isothiourea-catalysed enantioselective Michael addition of N-heterocyclic pronucleophiles to α,β-unsaturated aryl esters
por: Shu, Chang, et al.
Publicado: (2019)

Isothiourea-Catalyzed Enantioselective Michael Addition of Malonates to α,β-Unsaturated Aryl Esters
por: Wu, Jiufeng, et al.
Publicado: (2022)

Aryloxide‐Facilitated Catalyst Turnover in Enantioselective α,β‐Unsaturated Acyl Ammonium Catalysis
por: Matviitsuk, Anastassia, et al.
Publicado: (2017)

A catalytic enantioselective stereodivergent aldol reaction
por: Rahman, Md. Ataur, et al.
Publicado: (2023)

Cooperative Palladium/Isothiourea Catalyzed Enantioselective Formal (3+2) Cycloaddition of Vinylcyclopropanes and α,β‐Unsaturated Esters
por: Bitai, Jacqueline, et al.
Publicado: (2022)

Isothiourea‐Catalysed Acylative Kinetic Resolution of Aryl–Alkenyl (sp(2) vs. sp(2)) Substituted Secondary Alcohols
por: Musolino, Stefania F., et al.
Publicado: (2016)

Enantioselective Synthesis of α‐Aryl‐β(2)‐Amino‐Esters by Cooperative Isothiourea and Brønsted Acid Catalysis
por: Zhao, Feng, et al.
Publicado: (2021)

Exploring the Scope of Tandem Palladium and Isothiourea Relay Catalysis for the Synthesis of α-Amino Acid Derivatives
por: Bitai, Jacqueline, et al.
Publicado: (2020)

Tandem Palladium and Isothiourea Relay Catalysis: Enantioselective Synthesis of α-Amino Acid Derivatives via Allylic Amination and [2,3]-Sigmatropic Rearrangement
por: Spoehrle, Stéphanie S. M., et al.
Publicado: (2017)

Isothiourea-Catalyzed Enantioselective α-Alkylation of Esters via 1,6-Conjugate Addition to para-Quinone Methides
por: Arokianathar, Jude N., et al.
Publicado: (2021)

HBF(4)-Catalysed Nucleophilic Substitutions of Propargylic Alcohols
por: Barreiro, Elena, et al.
Publicado: (2015)

Isothiourea-Catalyzed [2 + 2] Cycloaddition of C(1)-Ammonium Enolates and N-Alkyl Isatins
por: Abdelhamid, Yusra, et al.
Publicado: (2022)

Isothiourea-Mediated One-Pot Synthesis of Functionalized Pyridines**
por: Stark, Daniel G, et al.
Publicado: (2013)

Copper-catalyzed enantioselective stereodivergent synthesis of amino alcohols
por: Shi, Shi-Liang, et al.
Publicado: (2016)

Visible light-driven Giese reaction with alkyl tosylates catalysed by nucleophilic cobalt
por: Komeyama, Kimihiro, et al.
Publicado: (2021)

Stereodivergent Organocatalytic Intramolecular Michael Addition/Lactonization for the Asymmetric Synthesis of Substituted Dihydrobenzofurans and Tetrahydrofurans
por: Belmessieri, Dorine, et al.
Publicado: (2014)

Non-bonding 1,5-S···O interactions govern chemo- and enantioselectivity in isothiourea-catalyzed annulations of benzazoles
por: Robinson, Emily R. T., et al.
Publicado: (2016)

6-exo-trig Michael addition-lactonizations for catalytic enantioselective chromenone synthesis
por: Neyyappadath, Rifahath M., et al.
Publicado: (2017)

Orthogonal Catalysis for an Enantioselective Domino Inverse‐Electron Demand Diels−Alder/Substitution Reaction
por: Beeck, Sebastian, et al.
Publicado: (2021)

Hydrofluorination of Alkynes Catalysed by Gold Bifluorides
por: Nahra, Fady, et al.
Publicado: (2015)

Nickel‐Catalyzed Stereodivergent Synthesis of E‐ and Z‐Alkenes by Hydrogenation of Alkynes
por: Murugesan, Kathiravan, et al.
Publicado: (2019)

Catalytic enantioselective nucleophilic desymmetrization of phosphonate esters
por: Formica, Michele, et al.
Publicado: (2023)

Enantioselective synthesis of (–)-chloramphenicol via silver-catalysed asymmetric isocyanoacetate aldol reaction
por: Franchino, Allegra, et al.
Publicado: (2015)

Microwave-assisted three-component domino reaction: Synthesis of indolodiazepinotriazoles
por: Arigela, Rajesh K, et al.
Publicado: (2013)

First chemoenzymatic stereodivergent synthesis of both enantiomers of promethazine and ethopropazine
por: Borowiecki, Paweł, et al.
Publicado: (2014)

Hydrazides in the reaction with hydroxypyrrolines: less nucleophilicity – more diversity
por: Shabalin, Dmitrii A, et al.
Publicado: (2021)

Synthesis of (–)-Indolizidine 167B based on domino hydroformylation/cyclization reactions
por: Guazzelli, Giuditta, et al.
Publicado: (2008)

Flexible synthesis of anthracycline aglycone mimics via domino carbopalladation reactions
por: Leibeling, Markus, et al.
Publicado: (2013)

Kinetics Studies on a Multicomponent Knoevenagel−Michael Domino Reaction by an Automated Flow Reactor
por: Haas, Christian P., et al.
Publicado: (2019)

Catalytic Enantioselective Synthesis of Heterocyclic Vicinal Fluoroamines by Using Asymmetric Protonation: Method Development and Mechanistic Study
por: Ashford, Matthew W., et al.
Publicado: (2020)

A Cu(II)–ATP complex efficiently catalyses enantioselective Diels–Alder reactions
por: Wang, Changhao, et al.
Publicado: (2020)

Evaluation of fluoropyruvate as nucleophile in reactions catalysed by N-acetyl neuraminic acid lyase variants: scope, limitations and stereoselectivity
por: Stockwell, Jennifer, et al.
Publicado: (2016)

Electron-rich triarylphosphines as nucleophilic catalysts for oxa-Michael reactions
por: Fischer, Susanne M, et al.
Publicado: (2021)

Efficient synthesis of pyrazolopyridines containing a chromane backbone through domino reaction
por: Navari, Razieh, et al.
Publicado: (2019)

Probing Regio- and Enantioselectivity in the Formal [2 + 2] Cycloaddition of C(1)-Alkyl Ammonium Enolates with β- and α,β-Substituted Trifluoromethylenones
por: Wang, Yihong, et al.
Publicado: (2023)

Further Studies on the Pyrolytic Domino Cyclization of Stabilized Phosphonium Ylides Bearing an Ortho-Aminophenyl Group
por: Aitken, R. Alan, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_uqpfuuvqc22icqisvr3bhhbqrh