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Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond: An Equivalent of Grignard Formation in Solution
[Image: see text] Addition of the carbon–fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg–Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon–magnesium bond and a new fluorine–magnesium bond...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5135227/ https://www.ncbi.nlm.nih.gov/pubmed/27636244 http://dx.doi.org/10.1021/jacs.6b08104 |
| _version_ | 1782471575855955968 |
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| author | Bakewell, Clare White, Andrew J. P. Crimmin, Mark R. |
| author_facet | Bakewell, Clare White, Andrew J. P. Crimmin, Mark R. |
| author_sort | Bakewell, Clare |
| collection | PubMed |
| description | [Image: see text] Addition of the carbon–fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg–Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon–magnesium bond and a new fluorine–magnesium bond and is analogous to Grignard formation in homogeneous solution. |
| format | Online Article Text |
| id | pubmed-5135227 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | American Chemical
Society |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-51352272016-12-05 Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond: An Equivalent of Grignard Formation in Solution Bakewell, Clare White, Andrew J. P. Crimmin, Mark R. J Am Chem Soc [Image: see text] Addition of the carbon–fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg–Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon–magnesium bond and a new fluorine–magnesium bond and is analogous to Grignard formation in homogeneous solution. American Chemical Society 2016-09-16 2016-10-05 /pmc/articles/PMC5135227/ /pubmed/27636244 http://dx.doi.org/10.1021/jacs.6b08104 Text en Copyright © 2016 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited. |
| spellingShingle | Bakewell, Clare White, Andrew J. P. Crimmin, Mark R. Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond: An Equivalent of Grignard Formation in Solution |
| title | Addition
of Carbon–Fluorine Bonds to a Mg(I)–Mg(I)
Bond: An Equivalent of Grignard Formation in Solution |
| title_full | Addition
of Carbon–Fluorine Bonds to a Mg(I)–Mg(I)
Bond: An Equivalent of Grignard Formation in Solution |
| title_fullStr | Addition
of Carbon–Fluorine Bonds to a Mg(I)–Mg(I)
Bond: An Equivalent of Grignard Formation in Solution |
| title_full_unstemmed | Addition
of Carbon–Fluorine Bonds to a Mg(I)–Mg(I)
Bond: An Equivalent of Grignard Formation in Solution |
| title_short | Addition
of Carbon–Fluorine Bonds to a Mg(I)–Mg(I)
Bond: An Equivalent of Grignard Formation in Solution |
| title_sort | addition
of carbon–fluorine bonds to a mg(i)–mg(i)
bond: an equivalent of grignard formation in solution |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5135227/ https://www.ncbi.nlm.nih.gov/pubmed/27636244 http://dx.doi.org/10.1021/jacs.6b08104 |
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