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Crystal structure of aquatris{μ-N-[bis(diethylamino)phosphoryl]-2,2,2-trichloroacetamidato-κ(3) O,O′:O}calciumsodium
In the molecular structure of the title compound, [CaNa(C(10)H(20)Cl(3)N(3)O(2)P)(3)(H(2)O)], the Ca(2+) ion has a slightly distorted octahedral coordination environment defined by six O atoms which belong to the carbonyl and phosphoryl groups of the three coordinating ligands. Two Cl atoms of CCl...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137587/ https://www.ncbi.nlm.nih.gov/pubmed/27980809 http://dx.doi.org/10.1107/S2056989016017035 |
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author | Shatrava, Iuliia Gubina, Kateryna Ovchynnikov, Vladimir Dyakonenko, Viktoriya Amirkhanov, Vladimir |
author_facet | Shatrava, Iuliia Gubina, Kateryna Ovchynnikov, Vladimir Dyakonenko, Viktoriya Amirkhanov, Vladimir |
author_sort | Shatrava, Iuliia |
collection | PubMed |
description | In the molecular structure of the title compound, [CaNa(C(10)H(20)Cl(3)N(3)O(2)P)(3)(H(2)O)], the Ca(2+) ion has a slightly distorted octahedral coordination environment defined by six O atoms which belong to the carbonyl and phosphoryl groups of the three coordinating ligands. Two Cl atoms of CCl(3) groups and four O atoms form the coordination environment of the Na(+) ion: three from the carbonyl groups of ligands and one O atom from a coordinating water molecule. In the crystal, the bimetallic complexes are assembled into chains along the c-axis direction via O—H⋯O hydrogen bonds that involve the coordinating water molecules and the phosphoryl groups. |
format | Online Article Text |
id | pubmed-5137587 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-51375872016-12-15 Crystal structure of aquatris{μ-N-[bis(diethylamino)phosphoryl]-2,2,2-trichloroacetamidato-κ(3) O,O′:O}calciumsodium Shatrava, Iuliia Gubina, Kateryna Ovchynnikov, Vladimir Dyakonenko, Viktoriya Amirkhanov, Vladimir Acta Crystallogr E Crystallogr Commun Research Communications In the molecular structure of the title compound, [CaNa(C(10)H(20)Cl(3)N(3)O(2)P)(3)(H(2)O)], the Ca(2+) ion has a slightly distorted octahedral coordination environment defined by six O atoms which belong to the carbonyl and phosphoryl groups of the three coordinating ligands. Two Cl atoms of CCl(3) groups and four O atoms form the coordination environment of the Na(+) ion: three from the carbonyl groups of ligands and one O atom from a coordinating water molecule. In the crystal, the bimetallic complexes are assembled into chains along the c-axis direction via O—H⋯O hydrogen bonds that involve the coordinating water molecules and the phosphoryl groups. International Union of Crystallography 2016-11-01 /pmc/articles/PMC5137587/ /pubmed/27980809 http://dx.doi.org/10.1107/S2056989016017035 Text en © Shatrava et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Shatrava, Iuliia Gubina, Kateryna Ovchynnikov, Vladimir Dyakonenko, Viktoriya Amirkhanov, Vladimir Crystal structure of aquatris{μ-N-[bis(diethylamino)phosphoryl]-2,2,2-trichloroacetamidato-κ(3) O,O′:O}calciumsodium |
title | Crystal structure of aquatris{μ-N-[bis(diethylamino)phosphoryl]-2,2,2-trichloroacetamidato-κ(3)
O,O′:O}calciumsodium |
title_full | Crystal structure of aquatris{μ-N-[bis(diethylamino)phosphoryl]-2,2,2-trichloroacetamidato-κ(3)
O,O′:O}calciumsodium |
title_fullStr | Crystal structure of aquatris{μ-N-[bis(diethylamino)phosphoryl]-2,2,2-trichloroacetamidato-κ(3)
O,O′:O}calciumsodium |
title_full_unstemmed | Crystal structure of aquatris{μ-N-[bis(diethylamino)phosphoryl]-2,2,2-trichloroacetamidato-κ(3)
O,O′:O}calciumsodium |
title_short | Crystal structure of aquatris{μ-N-[bis(diethylamino)phosphoryl]-2,2,2-trichloroacetamidato-κ(3)
O,O′:O}calciumsodium |
title_sort | crystal structure of aquatris{μ-n-[bis(diethylamino)phosphoryl]-2,2,2-trichloroacetamidato-κ(3)
o,o′:o}calciumsodium |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137587/ https://www.ncbi.nlm.nih.gov/pubmed/27980809 http://dx.doi.org/10.1107/S2056989016017035 |
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