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Crystal structure of aqua­tris­{μ-N-[bis(diethyl­amino)phosphoryl]-2,2,2-tri­chloroacetamidato-κ(3) O,O′:O}calciumsodium

In the mol­ecular structure of the title compound, [CaNa(C(10)H(20)Cl(3)N(3)O(2)P)(3)(H(2)O)], the Ca(2+) ion has a slightly distorted octa­hedral coordination environment defined by six O atoms which belong to the carbonyl and phosphoryl groups of the three coordinating ligands. Two Cl atoms of CCl...

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Autores principales: Shatrava, Iuliia, Gubina, Kateryna, Ovchynnikov, Vladimir, Dyakonenko, Viktoriya, Amirkhanov, Vladimir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137587/
https://www.ncbi.nlm.nih.gov/pubmed/27980809
http://dx.doi.org/10.1107/S2056989016017035
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author Shatrava, Iuliia
Gubina, Kateryna
Ovchynnikov, Vladimir
Dyakonenko, Viktoriya
Amirkhanov, Vladimir
author_facet Shatrava, Iuliia
Gubina, Kateryna
Ovchynnikov, Vladimir
Dyakonenko, Viktoriya
Amirkhanov, Vladimir
author_sort Shatrava, Iuliia
collection PubMed
description In the mol­ecular structure of the title compound, [CaNa(C(10)H(20)Cl(3)N(3)O(2)P)(3)(H(2)O)], the Ca(2+) ion has a slightly distorted octa­hedral coordination environment defined by six O atoms which belong to the carbonyl and phosphoryl groups of the three coordinating ligands. Two Cl atoms of CCl(3) groups and four O atoms form the coordination environment of the Na(+) ion: three from the carbonyl groups of ligands and one O atom from a coordinating water mol­ecule. In the crystal, the bimetallic complexes are assembled into chains along the c-axis direction via O—H⋯O hydrogen bonds that involve the coordinating water mol­ecules and the phosphoryl groups.
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spelling pubmed-51375872016-12-15 Crystal structure of aqua­tris­{μ-N-[bis(diethyl­amino)phosphoryl]-2,2,2-tri­chloroacetamidato-κ(3) O,O′:O}calciumsodium Shatrava, Iuliia Gubina, Kateryna Ovchynnikov, Vladimir Dyakonenko, Viktoriya Amirkhanov, Vladimir Acta Crystallogr E Crystallogr Commun Research Communications In the mol­ecular structure of the title compound, [CaNa(C(10)H(20)Cl(3)N(3)O(2)P)(3)(H(2)O)], the Ca(2+) ion has a slightly distorted octa­hedral coordination environment defined by six O atoms which belong to the carbonyl and phosphoryl groups of the three coordinating ligands. Two Cl atoms of CCl(3) groups and four O atoms form the coordination environment of the Na(+) ion: three from the carbonyl groups of ligands and one O atom from a coordinating water mol­ecule. In the crystal, the bimetallic complexes are assembled into chains along the c-axis direction via O—H⋯O hydrogen bonds that involve the coordinating water mol­ecules and the phosphoryl groups. International Union of Crystallography 2016-11-01 /pmc/articles/PMC5137587/ /pubmed/27980809 http://dx.doi.org/10.1107/S2056989016017035 Text en © Shatrava et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shatrava, Iuliia
Gubina, Kateryna
Ovchynnikov, Vladimir
Dyakonenko, Viktoriya
Amirkhanov, Vladimir
Crystal structure of aqua­tris­{μ-N-[bis(diethyl­amino)phosphoryl]-2,2,2-tri­chloroacetamidato-κ(3) O,O′:O}calciumsodium
title Crystal structure of aqua­tris­{μ-N-[bis(diethyl­amino)phosphoryl]-2,2,2-tri­chloroacetamidato-κ(3) O,O′:O}calciumsodium
title_full Crystal structure of aqua­tris­{μ-N-[bis(diethyl­amino)phosphoryl]-2,2,2-tri­chloroacetamidato-κ(3) O,O′:O}calciumsodium
title_fullStr Crystal structure of aqua­tris­{μ-N-[bis(diethyl­amino)phosphoryl]-2,2,2-tri­chloroacetamidato-κ(3) O,O′:O}calciumsodium
title_full_unstemmed Crystal structure of aqua­tris­{μ-N-[bis(diethyl­amino)phosphoryl]-2,2,2-tri­chloroacetamidato-κ(3) O,O′:O}calciumsodium
title_short Crystal structure of aqua­tris­{μ-N-[bis(diethyl­amino)phosphoryl]-2,2,2-tri­chloroacetamidato-κ(3) O,O′:O}calciumsodium
title_sort crystal structure of aqua­tris­{μ-n-[bis(diethyl­amino)phosphoryl]-2,2,2-tri­chloroacetamidato-κ(3) o,o′:o}calciumsodium
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137587/
https://www.ncbi.nlm.nih.gov/pubmed/27980809
http://dx.doi.org/10.1107/S2056989016017035
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