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Crystal structure of 1,3-bis[(E)-4-methoxybenzylideneamino]propan-2-ol
The title Schiff base, C(19)H(22)N(2)O(3), was synthesized via the condensation reaction of 1,3-diaminopropan-2-ol with 4-methoxybenzaldehyde using water as solvent. The molecule exists in an E,E conformation with respect to the C=N imine bonds and the dihedral angle between the aromatic rings...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137596/ https://www.ncbi.nlm.nih.gov/pubmed/27980818 http://dx.doi.org/10.1107/S2056989016016947 |
Sumario: | The title Schiff base, C(19)H(22)N(2)O(3), was synthesized via the condensation reaction of 1,3-diaminopropan-2-ol with 4-methoxybenzaldehyde using water as solvent. The molecule exists in an E,E conformation with respect to the C=N imine bonds and the dihedral angle between the aromatic rings is 37.25 (15)°. In the crystal, O—H⋯N hydrogen bonds link the molecules into infinite C(5) chains propagating along the a-axis direction. The packing of these chains is consolidated by C—H⋯O interactions and C—H⋯π short contacts, forming a three-dimensional network. |
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