Crystal structure of 1,3-bis­[(E)-4-meth­oxy­benzyl­idene­amino]­propan-2-ol

The title Schiff base, C(19)H(22)N(2)O(3), was synthesized via the condensation reaction of 1,3-di­amino­propan-2-ol with 4-meth­oxy­benzaldehyde using water as solvent. The mol­ecule exists in an E,E conformation with respect to the C=N imine bonds and the dihedral angle between the aromatic rings...

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Autores principales: Rivera, Augusto, Miranda-Carvajal, Ingrid, Ríos-Motta, Jaime, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137596/
https://www.ncbi.nlm.nih.gov/pubmed/27980818
http://dx.doi.org/10.1107/S2056989016016947
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author Rivera, Augusto
Miranda-Carvajal, Ingrid
Ríos-Motta, Jaime
Bolte, Michael
author_facet Rivera, Augusto
Miranda-Carvajal, Ingrid
Ríos-Motta, Jaime
Bolte, Michael
author_sort Rivera, Augusto
collection PubMed
description The title Schiff base, C(19)H(22)N(2)O(3), was synthesized via the condensation reaction of 1,3-di­amino­propan-2-ol with 4-meth­oxy­benzaldehyde using water as solvent. The mol­ecule exists in an E,E conformation with respect to the C=N imine bonds and the dihedral angle between the aromatic rings is 37.25 (15)°. In the crystal, O—H⋯N hydrogen bonds link the mol­ecules into infinite C(5) chains propagating along the a-axis direction. The packing of these chains is consolidated by C—H⋯O inter­actions and C—H⋯π short contacts, forming a three-dimensional network.
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spelling pubmed-51375962016-12-15 Crystal structure of 1,3-bis­[(E)-4-meth­oxy­benzyl­idene­amino]­propan-2-ol Rivera, Augusto Miranda-Carvajal, Ingrid Ríos-Motta, Jaime Bolte, Michael Acta Crystallogr E Crystallogr Commun Research Communications The title Schiff base, C(19)H(22)N(2)O(3), was synthesized via the condensation reaction of 1,3-di­amino­propan-2-ol with 4-meth­oxy­benzaldehyde using water as solvent. The mol­ecule exists in an E,E conformation with respect to the C=N imine bonds and the dihedral angle between the aromatic rings is 37.25 (15)°. In the crystal, O—H⋯N hydrogen bonds link the mol­ecules into infinite C(5) chains propagating along the a-axis direction. The packing of these chains is consolidated by C—H⋯O inter­actions and C—H⋯π short contacts, forming a three-dimensional network. International Union of Crystallography 2016-11-04 /pmc/articles/PMC5137596/ /pubmed/27980818 http://dx.doi.org/10.1107/S2056989016016947 Text en © Rivera et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Rivera, Augusto
Miranda-Carvajal, Ingrid
Ríos-Motta, Jaime
Bolte, Michael
Crystal structure of 1,3-bis­[(E)-4-meth­oxy­benzyl­idene­amino]­propan-2-ol
title Crystal structure of 1,3-bis­[(E)-4-meth­oxy­benzyl­idene­amino]­propan-2-ol
title_full Crystal structure of 1,3-bis­[(E)-4-meth­oxy­benzyl­idene­amino]­propan-2-ol
title_fullStr Crystal structure of 1,3-bis­[(E)-4-meth­oxy­benzyl­idene­amino]­propan-2-ol
title_full_unstemmed Crystal structure of 1,3-bis­[(E)-4-meth­oxy­benzyl­idene­amino]­propan-2-ol
title_short Crystal structure of 1,3-bis­[(E)-4-meth­oxy­benzyl­idene­amino]­propan-2-ol
title_sort crystal structure of 1,3-bis­[(e)-4-meth­oxy­benzyl­idene­amino]­propan-2-ol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137596/
https://www.ncbi.nlm.nih.gov/pubmed/27980818
http://dx.doi.org/10.1107/S2056989016016947
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AT riosmottajaime crystalstructureof13bise4methoxybenzylideneaminopropan2ol
AT boltemichael crystalstructureof13bise4methoxybenzylideneaminopropan2ol

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