Cargando…
Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ(2) C (1),N]bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
In the title compound, [Ir(C(11)H(8)N)(2)(C(18)H(14)N)], the Ir(III) ion adopts a distorted octahedral coordination environment defined by three C,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methylpyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a faci...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137604/ https://www.ncbi.nlm.nih.gov/pubmed/27980826 http://dx.doi.org/10.1107/S2056989016017618 |
Sumario: | In the title compound, [Ir(C(11)H(8)N)(2)(C(18)H(14)N)], the Ir(III) ion adopts a distorted octahedral coordination environment defined by three C,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methylpyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a facial manner. The Ir(III) ion lies almost in the equatorial plane [deviation = 0.0069 (15) Å]. In the crystal, intermolecular π–π stacking interactions, as well as intermolecular C—H⋯π interactions, are present, leading to a three-dimensional network. |
---|