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Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ(2) C (1),N]bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III)
In the title compound, [Ir(C(11)H(8)N)(2)(C(18)H(14)N)], the Ir(III) ion adopts a distorted octahedral coordination environment defined by three C,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methylpyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a faci...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137604/ https://www.ncbi.nlm.nih.gov/pubmed/27980826 http://dx.doi.org/10.1107/S2056989016017618 |
| _version_ | 1782471945053274112 |
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| author | Lee, Chi-Heon Moon, Suk-Hee Park, Ki-Min Kang, Youngjin |
| author_facet | Lee, Chi-Heon Moon, Suk-Hee Park, Ki-Min Kang, Youngjin |
| author_sort | Lee, Chi-Heon |
| collection | PubMed |
| description | In the title compound, [Ir(C(11)H(8)N)(2)(C(18)H(14)N)], the Ir(III) ion adopts a distorted octahedral coordination environment defined by three C,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methylpyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a facial manner. The Ir(III) ion lies almost in the equatorial plane [deviation = 0.0069 (15) Å]. In the crystal, intermolecular π–π stacking interactions, as well as intermolecular C—H⋯π interactions, are present, leading to a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-5137604 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-51376042016-12-15 Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ(2) C (1),N]bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) Lee, Chi-Heon Moon, Suk-Hee Park, Ki-Min Kang, Youngjin Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Ir(C(11)H(8)N)(2)(C(18)H(14)N)], the Ir(III) ion adopts a distorted octahedral coordination environment defined by three C,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methylpyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a facial manner. The Ir(III) ion lies almost in the equatorial plane [deviation = 0.0069 (15) Å]. In the crystal, intermolecular π–π stacking interactions, as well as intermolecular C—H⋯π interactions, are present, leading to a three-dimensional network. International Union of Crystallography 2016-11-08 /pmc/articles/PMC5137604/ /pubmed/27980826 http://dx.doi.org/10.1107/S2056989016017618 Text en © Lee et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Lee, Chi-Heon Moon, Suk-Hee Park, Ki-Min Kang, Youngjin Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ(2) C (1),N]bis[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]iridium(III) |
| title | Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ(2)
C
(1),N]bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_full | Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ(2)
C
(1),N]bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_fullStr | Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ(2)
C
(1),N]bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_full_unstemmed | Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ(2)
C
(1),N]bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_short | Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ(2)
C
(1),N]bis[2-(pyridin-2-yl)phenyl-κ(2)
C
(1),N]iridium(III) |
| title_sort | crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ(2)
c
(1),n]bis[2-(pyridin-2-yl)phenyl-κ(2)
c
(1),n]iridium(iii) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137604/ https://www.ncbi.nlm.nih.gov/pubmed/27980826 http://dx.doi.org/10.1107/S2056989016017618 |
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