Crystal structure of catena-poly[di­ammonium [di-μ-oxalato-cuprate(II)]]

The structure of the title compound, {(NH(4))(2)[Cu(C(2)O(4))(2)]}(n), at 100 K has monoclinic (P2(1)/c) symmetry with the Cu(II) atom on an inversion center. The compound has a polymeric structure due to long Cu⋯O inter­actions which create [Cu(C(2)O(4))(2)] chains along the a axis. The structure a...

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Detalles Bibliográficos
Autores principales: Dickie, Diane A., Kemp, Richard A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137607/
https://www.ncbi.nlm.nih.gov/pubmed/27980829
http://dx.doi.org/10.1107/S2056989016017631
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author Dickie, Diane A.
Kemp, Richard A.
author_facet Dickie, Diane A.
Kemp, Richard A.
author_sort Dickie, Diane A.
collection PubMed
description The structure of the title compound, {(NH(4))(2)[Cu(C(2)O(4))(2)]}(n), at 100 K has monoclinic (P2(1)/c) symmetry with the Cu(II) atom on an inversion center. The compound has a polymeric structure due to long Cu⋯O inter­actions which create [Cu(C(2)O(4))(2)] chains along the a axis. The structure also displays inter­molecular N—H⋯O hydrogen bonding, which links these chains into a three-dimensional network.
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spelling pubmed-51376072016-12-15 Crystal structure of catena-poly[di­ammonium [di-μ-oxalato-cuprate(II)]] Dickie, Diane A. Kemp, Richard A. Acta Crystallogr E Crystallogr Commun Research Communications The structure of the title compound, {(NH(4))(2)[Cu(C(2)O(4))(2)]}(n), at 100 K has monoclinic (P2(1)/c) symmetry with the Cu(II) atom on an inversion center. The compound has a polymeric structure due to long Cu⋯O inter­actions which create [Cu(C(2)O(4))(2)] chains along the a axis. The structure also displays inter­molecular N—H⋯O hydrogen bonding, which links these chains into a three-dimensional network. International Union of Crystallography 2016-11-10 /pmc/articles/PMC5137607/ /pubmed/27980829 http://dx.doi.org/10.1107/S2056989016017631 Text en © Dickie and Kemp 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Dickie, Diane A.
Kemp, Richard A.
Crystal structure of catena-poly[di­ammonium [di-μ-oxalato-cuprate(II)]]
title Crystal structure of catena-poly[di­ammonium [di-μ-oxalato-cuprate(II)]]
title_full Crystal structure of catena-poly[di­ammonium [di-μ-oxalato-cuprate(II)]]
title_fullStr Crystal structure of catena-poly[di­ammonium [di-μ-oxalato-cuprate(II)]]
title_full_unstemmed Crystal structure of catena-poly[di­ammonium [di-μ-oxalato-cuprate(II)]]
title_short Crystal structure of catena-poly[di­ammonium [di-μ-oxalato-cuprate(II)]]
title_sort crystal structure of catena-poly[di­ammonium [di-μ-oxalato-cuprate(ii)]]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137607/
https://www.ncbi.nlm.nih.gov/pubmed/27980829
http://dx.doi.org/10.1107/S2056989016017631
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