Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) tetra­iodide

The title salt, [Mn(C(2)H(6)OS)(6)]I(4), is made up from discrete [Mn(DMSO)(6)](2+) (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I(4) (2−) tetra­iodide anions. The Mn(II) ion in the cation, situated on a position with site symmetry -3., is octa­hedrally...

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Detalles Bibliográficos
Autores principales: Haque, Md Azimul, Davaasuren, Bambar, Rothenberger, Alexander, Wu, Tom
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137610/
https://www.ncbi.nlm.nih.gov/pubmed/27980832
http://dx.doi.org/10.1107/S2056989016017904
Descripción
Sumario:The title salt, [Mn(C(2)H(6)OS)(6)]I(4), is made up from discrete [Mn(DMSO)(6)](2+) (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I(4) (2−) tetra­iodide anions. The Mn(II) ion in the cation, situated on a position with site symmetry -3., is octa­hedrally coordinated by O atoms of the DMSO mol­ecule with an Mn—O distance of 2.1808 (12) Å. The I(4) (2−) anion contains a neutral I(2) mol­ecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetra­iodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.

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