Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) tetra­iodide

The title salt, [Mn(C(2)H(6)OS)(6)]I(4), is made up from discrete [Mn(DMSO)(6)](2+) (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I(4) (2−) tetra­iodide anions. The Mn(II) ion in the cation, situated on a position with site symmetry -3., is octa­hedrally...

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Autores principales: Haque, Md Azimul, Davaasuren, Bambar, Rothenberger, Alexander, Wu, Tom
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137610/
https://www.ncbi.nlm.nih.gov/pubmed/27980832
http://dx.doi.org/10.1107/S2056989016017904
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author Haque, Md Azimul
Davaasuren, Bambar
Rothenberger, Alexander
Wu, Tom
author_facet Haque, Md Azimul
Davaasuren, Bambar
Rothenberger, Alexander
Wu, Tom
author_sort Haque, Md Azimul
collection PubMed
description The title salt, [Mn(C(2)H(6)OS)(6)]I(4), is made up from discrete [Mn(DMSO)(6)](2+) (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I(4) (2−) tetra­iodide anions. The Mn(II) ion in the cation, situated on a position with site symmetry -3., is octa­hedrally coordinated by O atoms of the DMSO mol­ecule with an Mn—O distance of 2.1808 (12) Å. The I(4) (2−) anion contains a neutral I(2) mol­ecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetra­iodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues.
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spelling pubmed-51376102016-12-15 Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) tetra­iodide Haque, Md Azimul Davaasuren, Bambar Rothenberger, Alexander Wu, Tom Acta Crystallogr E Crystallogr Commun Research Communications The title salt, [Mn(C(2)H(6)OS)(6)]I(4), is made up from discrete [Mn(DMSO)(6)](2+) (DMSO is dimethyl sulfoxide) units connected through non-classical hydrogen bonds to linear I(4) (2−) tetra­iodide anions. The Mn(II) ion in the cation, situated on a position with site symmetry -3., is octa­hedrally coordinated by O atoms of the DMSO mol­ecule with an Mn—O distance of 2.1808 (12) Å. The I(4) (2−) anion contains a neutral I(2) mol­ecule weakly coordinated by two iodide ions, forming a linear centrosymmetric tetra­iodide anion. The title compound is isotypic with the Co, Ni, Cu, and Zn analogues. International Union of Crystallography 2016-11-15 /pmc/articles/PMC5137610/ /pubmed/27980832 http://dx.doi.org/10.1107/S2056989016017904 Text en © Haque et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Haque, Md Azimul
Davaasuren, Bambar
Rothenberger, Alexander
Wu, Tom
Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) tetra­iodide
title Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) tetra­iodide
title_full Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) tetra­iodide
title_fullStr Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) tetra­iodide
title_full_unstemmed Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) tetra­iodide
title_short Crystal structure of hexa­kis­(dimethyl sulfoxide-κO)manganese(II) tetra­iodide
title_sort crystal structure of hexa­kis­(dimethyl sulfoxide-κo)manganese(ii) tetra­iodide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137610/
https://www.ncbi.nlm.nih.gov/pubmed/27980832
http://dx.doi.org/10.1107/S2056989016017904
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