Synthesis and crystal structure of a new alluaudite-like iron phosphate Na(2)CaMnFe(PO(4))(3)

A new iron phosphate, disodium calcium manganese(II) iron(III) tris(phosphate), Na(2)CaMnFe(PO(4))(3), has been synthesized as single crystals by the flux technique. This compound crystallizes in the monoclinic space group C2/c. The structure belongs to the alluaudite structural type and thus, it ob...

Descripción completa

Detalles Bibliográficos
Autores principales: Jebli, Semeh, Badri, Abdessalem, Ben Amara, Mongi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137613/
https://www.ncbi.nlm.nih.gov/pubmed/27980835
http://dx.doi.org/10.1107/S2056989016017771
Descripción
Sumario:A new iron phosphate, disodium calcium manganese(II) iron(III) tris(phosphate), Na(2)CaMnFe(PO(4))(3), has been synthesized as single crystals by the flux technique. This compound crystallizes in the monoclinic space group C2/c. The structure belongs to the alluaudite structural type and thus, it obeys the X(2)X(1)M(1)M(2)(2)(PO(4))(3) general formula. Both the X(2) and X(1) sites are fully occupied by sodium, while M(1) is occupied by calcium and M(2) exhibits a statistical distribution of iron and manganese.

Ejemplares similares