Synthesis and crystal structure of a new alluaudite-like iron phosphate Na(2)CaMnFe(PO(4))(3)

A new iron phosphate, disodium calcium manganese(II) iron(III) tris(phosphate), Na(2)CaMnFe(PO(4))(3), has been synthesized as single crystals by the flux technique. This compound crystallizes in the monoclinic space group C2/c. The structure belongs to the alluaudite structural type and thus, it ob...

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Detalles Bibliográficos
Autores principales: Jebli, Semeh, Badri, Abdessalem, Ben Amara, Mongi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137613/
https://www.ncbi.nlm.nih.gov/pubmed/27980835
http://dx.doi.org/10.1107/S2056989016017771
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author Jebli, Semeh
Badri, Abdessalem
Ben Amara, Mongi
author_facet Jebli, Semeh
Badri, Abdessalem
Ben Amara, Mongi
author_sort Jebli, Semeh
collection PubMed
description A new iron phosphate, disodium calcium manganese(II) iron(III) tris(phosphate), Na(2)CaMnFe(PO(4))(3), has been synthesized as single crystals by the flux technique. This compound crystallizes in the monoclinic space group C2/c. The structure belongs to the alluaudite structural type and thus, it obeys the X(2)X(1)M(1)M(2)(2)(PO(4))(3) general formula. Both the X(2) and X(1) sites are fully occupied by sodium, while M(1) is occupied by calcium and M(2) exhibits a statistical distribution of iron and manganese.
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spelling pubmed-51376132016-12-15 Synthesis and crystal structure of a new alluaudite-like iron phosphate Na(2)CaMnFe(PO(4))(3) Jebli, Semeh Badri, Abdessalem Ben Amara, Mongi Acta Crystallogr E Crystallogr Commun Research Communications A new iron phosphate, disodium calcium manganese(II) iron(III) tris(phosphate), Na(2)CaMnFe(PO(4))(3), has been synthesized as single crystals by the flux technique. This compound crystallizes in the monoclinic space group C2/c. The structure belongs to the alluaudite structural type and thus, it obeys the X(2)X(1)M(1)M(2)(2)(PO(4))(3) general formula. Both the X(2) and X(1) sites are fully occupied by sodium, while M(1) is occupied by calcium and M(2) exhibits a statistical distribution of iron and manganese. International Union of Crystallography 2016-11-15 /pmc/articles/PMC5137613/ /pubmed/27980835 http://dx.doi.org/10.1107/S2056989016017771 Text en © Jebli et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Jebli, Semeh
Badri, Abdessalem
Ben Amara, Mongi
Synthesis and crystal structure of a new alluaudite-like iron phosphate Na(2)CaMnFe(PO(4))(3)
title Synthesis and crystal structure of a new alluaudite-like iron phosphate Na(2)CaMnFe(PO(4))(3)
title_full Synthesis and crystal structure of a new alluaudite-like iron phosphate Na(2)CaMnFe(PO(4))(3)
title_fullStr Synthesis and crystal structure of a new alluaudite-like iron phosphate Na(2)CaMnFe(PO(4))(3)
title_full_unstemmed Synthesis and crystal structure of a new alluaudite-like iron phosphate Na(2)CaMnFe(PO(4))(3)
title_short Synthesis and crystal structure of a new alluaudite-like iron phosphate Na(2)CaMnFe(PO(4))(3)
title_sort synthesis and crystal structure of a new alluaudite-like iron phosphate na(2)camnfe(po(4))(3)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137613/
https://www.ncbi.nlm.nih.gov/pubmed/27980835
http://dx.doi.org/10.1107/S2056989016017771
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