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Crystal structure of N,N′-dibenzylpyromellitic diimide
The title compound, C(24)H(16)N(2)O(4) [systematic name: 2,6-dibenzylpyrrolo[3,4-f]isoindole-1,3,5,7(2H,6H)-tetraone], consists of a central pyromellitic diimide moiety with terminal benzyl groups at the N-atom positions. The molecule is located about an inversion centre, so the asymmetric un...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137614/ https://www.ncbi.nlm.nih.gov/pubmed/27980836 http://dx.doi.org/10.1107/S2056989016017710 |
Sumario: | The title compound, C(24)H(16)N(2)O(4) [systematic name: 2,6-dibenzylpyrrolo[3,4-f]isoindole-1,3,5,7(2H,6H)-tetraone], consists of a central pyromellitic diimide moiety with terminal benzyl groups at the N-atom positions. The molecule is located about an inversion centre, so the asymmetric unit contains one half-molecule. In the molecule, both terminal phenyl groups, tilted by 72.97 (4)° with respect to the mean plane of the central pyromellitic diimide moiety (r.m.s. deviation = 0.0145 Å), are oriented away from each other, forming an elongated S-shaped conformation. In the crystal, molecules are connected via weak C—H⋯O hydrogen bonds and C—H⋯π interactions, resulting in the formation of supramolecular layers extending parallel to the ab plane. |
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