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Crystal structure of N,N′-di­benzyl­pyromellitic diimide

The title compound, C(24)H(16)N(2)O(4) [systematic name: 2,6-di­benzyl­pyrrolo­[3,4-f]iso­indole-1,3,5,7(2H,6H)-tetra­one], consists of a central pyromellitic di­imide moiety with terminal benzyl groups at the N-atom positions. The mol­ecule is located about an inversion centre, so the asymmetric un...

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Detalles Bibliográficos
Autores principales: Im, Hansu, Moon, Suk-Hee, Kim, Tae Ho, Park, Ki-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137614/
https://www.ncbi.nlm.nih.gov/pubmed/27980836
http://dx.doi.org/10.1107/S2056989016017710
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author Im, Hansu
Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
author_facet Im, Hansu
Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
author_sort Im, Hansu
collection PubMed
description The title compound, C(24)H(16)N(2)O(4) [systematic name: 2,6-di­benzyl­pyrrolo­[3,4-f]iso­indole-1,3,5,7(2H,6H)-tetra­one], consists of a central pyromellitic di­imide moiety with terminal benzyl groups at the N-atom positions. The mol­ecule is located about an inversion centre, so the asymmetric unit contains one half-mol­ecule. In the mol­ecule, both terminal phenyl groups, tilted by 72.97 (4)° with respect to the mean plane of the central pyromellitic di­imide moiety (r.m.s. deviation = 0.0145 Å), are oriented away from each other, forming an elongated S-shaped conformation. In the crystal, mol­ecules are connected via weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions, resulting in the formation of supra­molecular layers extending parallel to the ab plane.
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spelling pubmed-51376142016-12-15 Crystal structure of N,N′-di­benzyl­pyromellitic diimide Im, Hansu Moon, Suk-Hee Kim, Tae Ho Park, Ki-Min Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(24)H(16)N(2)O(4) [systematic name: 2,6-di­benzyl­pyrrolo­[3,4-f]iso­indole-1,3,5,7(2H,6H)-tetra­one], consists of a central pyromellitic di­imide moiety with terminal benzyl groups at the N-atom positions. The mol­ecule is located about an inversion centre, so the asymmetric unit contains one half-mol­ecule. In the mol­ecule, both terminal phenyl groups, tilted by 72.97 (4)° with respect to the mean plane of the central pyromellitic di­imide moiety (r.m.s. deviation = 0.0145 Å), are oriented away from each other, forming an elongated S-shaped conformation. In the crystal, mol­ecules are connected via weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions, resulting in the formation of supra­molecular layers extending parallel to the ab plane. International Union of Crystallography 2016-11-15 /pmc/articles/PMC5137614/ /pubmed/27980836 http://dx.doi.org/10.1107/S2056989016017710 Text en © Im et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Im, Hansu
Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
Crystal structure of N,N′-di­benzyl­pyromellitic diimide
title Crystal structure of N,N′-di­benzyl­pyromellitic diimide
title_full Crystal structure of N,N′-di­benzyl­pyromellitic diimide
title_fullStr Crystal structure of N,N′-di­benzyl­pyromellitic diimide
title_full_unstemmed Crystal structure of N,N′-di­benzyl­pyromellitic diimide
title_short Crystal structure of N,N′-di­benzyl­pyromellitic diimide
title_sort crystal structure of n,n′-di­benzyl­pyromellitic diimide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137614/
https://www.ncbi.nlm.nih.gov/pubmed/27980836
http://dx.doi.org/10.1107/S2056989016017710
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