Synthesis and crystal structure of 4-fluoro­benzyl­ammonium di­hydrogen phosphate, [FC(6)H(4)CH(2)NH(3)]H(2)PO(4)

The asymmetric unit of the title salt, [p-FC(6)H(4)CH(2)NH(3)](+)·H(2)PO(4) (−), contains one 4-fluoro­benzyl­ammonium cation and one di­hydrogen phosphate anion. In the crystal, the H(2)PO(4) (−) anions are linked by O—H⋯O hydrogen bonds to build corrugated layers extending parallel to the ab plane...

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Autores principales: Rayes, Ali, Dadi, Ahlem, Mahbouli Rhouma, Najla, Mezzadri, Francesco, Calestani, Gianluca
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137615/
https://www.ncbi.nlm.nih.gov/pubmed/27980837
http://dx.doi.org/10.1107/S2056989016018090
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author Rayes, Ali
Dadi, Ahlem
Mahbouli Rhouma, Najla
Mezzadri, Francesco
Calestani, Gianluca
author_facet Rayes, Ali
Dadi, Ahlem
Mahbouli Rhouma, Najla
Mezzadri, Francesco
Calestani, Gianluca
author_sort Rayes, Ali
collection PubMed
description The asymmetric unit of the title salt, [p-FC(6)H(4)CH(2)NH(3)](+)·H(2)PO(4) (−), contains one 4-fluoro­benzyl­ammonium cation and one di­hydrogen phosphate anion. In the crystal, the H(2)PO(4) (−) anions are linked by O—H⋯O hydrogen bonds to build corrugated layers extending parallel to the ab plane. The FC(6)H(4)CH(2)NH(3) (+) cations lie between these anionic layers to maximize the electrostatic inter­actions and are linked to the H(2)PO(4) (−) anions through N—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. Two hydrogen atoms belonging to the di­hydrogen phosphate anion are statistically occupied due to disorder along the OH⋯HO direction.
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spelling pubmed-51376152016-12-15 Synthesis and crystal structure of 4-fluoro­benzyl­ammonium di­hydrogen phosphate, [FC(6)H(4)CH(2)NH(3)]H(2)PO(4) Rayes, Ali Dadi, Ahlem Mahbouli Rhouma, Najla Mezzadri, Francesco Calestani, Gianluca Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title salt, [p-FC(6)H(4)CH(2)NH(3)](+)·H(2)PO(4) (−), contains one 4-fluoro­benzyl­ammonium cation and one di­hydrogen phosphate anion. In the crystal, the H(2)PO(4) (−) anions are linked by O—H⋯O hydrogen bonds to build corrugated layers extending parallel to the ab plane. The FC(6)H(4)CH(2)NH(3) (+) cations lie between these anionic layers to maximize the electrostatic inter­actions and are linked to the H(2)PO(4) (−) anions through N—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. Two hydrogen atoms belonging to the di­hydrogen phosphate anion are statistically occupied due to disorder along the OH⋯HO direction. International Union of Crystallography 2016-11-15 /pmc/articles/PMC5137615/ /pubmed/27980837 http://dx.doi.org/10.1107/S2056989016018090 Text en © Rayes et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Rayes, Ali
Dadi, Ahlem
Mahbouli Rhouma, Najla
Mezzadri, Francesco
Calestani, Gianluca
Synthesis and crystal structure of 4-fluoro­benzyl­ammonium di­hydrogen phosphate, [FC(6)H(4)CH(2)NH(3)]H(2)PO(4)
title Synthesis and crystal structure of 4-fluoro­benzyl­ammonium di­hydrogen phosphate, [FC(6)H(4)CH(2)NH(3)]H(2)PO(4)
title_full Synthesis and crystal structure of 4-fluoro­benzyl­ammonium di­hydrogen phosphate, [FC(6)H(4)CH(2)NH(3)]H(2)PO(4)
title_fullStr Synthesis and crystal structure of 4-fluoro­benzyl­ammonium di­hydrogen phosphate, [FC(6)H(4)CH(2)NH(3)]H(2)PO(4)
title_full_unstemmed Synthesis and crystal structure of 4-fluoro­benzyl­ammonium di­hydrogen phosphate, [FC(6)H(4)CH(2)NH(3)]H(2)PO(4)
title_short Synthesis and crystal structure of 4-fluoro­benzyl­ammonium di­hydrogen phosphate, [FC(6)H(4)CH(2)NH(3)]H(2)PO(4)
title_sort synthesis and crystal structure of 4-fluoro­benzyl­ammonium di­hydrogen phosphate, [fc(6)h(4)ch(2)nh(3)]h(2)po(4)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137615/
https://www.ncbi.nlm.nih.gov/pubmed/27980837
http://dx.doi.org/10.1107/S2056989016018090
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