Crystal structure of bis­(3,5-di­methyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)

The asymmetric unit of the title complex, [Co(NCS)(2)(C(7)H(9)N)(2)(CH(3)OH)(2)], comprises of one Co(II) cation located on a centre of inversion, one thio­cyanate ligand, one methanol ligand and one 3,5-di­methyl­pyridine ligand. The Co(II) cation is octa­hedrally coordinated by two terminal N-bond...

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Detalles Bibliográficos
Autores principales: Suckert, Stefan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137618/
https://www.ncbi.nlm.nih.gov/pubmed/27980840
http://dx.doi.org/10.1107/S2056989016018326
Descripción
Sumario:The asymmetric unit of the title complex, [Co(NCS)(2)(C(7)H(9)N)(2)(CH(3)OH)(2)], comprises of one Co(II) cation located on a centre of inversion, one thio­cyanate ligand, one methanol ligand and one 3,5-di­methyl­pyridine ligand. The Co(II) cation is octa­hedrally coordinated by two terminal N-bonding thio­cyanate anions, two methanol mol­ecules and two 3,5-di­methyl­pyridine ligands into a discrete complex. The complex mol­ecules are linked by inter­molecular O—H⋯S hydrogen bonding into chains that elongate in the direction parallel to the b axis.

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