Crystal structure of bis­(3,5-di­methyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)

The asymmetric unit of the title complex, [Co(NCS)(2)(C(7)H(9)N)(2)(CH(3)OH)(2)], comprises of one Co(II) cation located on a centre of inversion, one thio­cyanate ligand, one methanol ligand and one 3,5-di­methyl­pyridine ligand. The Co(II) cation is octa­hedrally coordinated by two terminal N-bond...

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Detalles Bibliográficos
Autores principales: Suckert, Stefan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137618/
https://www.ncbi.nlm.nih.gov/pubmed/27980840
http://dx.doi.org/10.1107/S2056989016018326
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author Suckert, Stefan
Jess, Inke
Näther, Christian
author_facet Suckert, Stefan
Jess, Inke
Näther, Christian
author_sort Suckert, Stefan
collection PubMed
description The asymmetric unit of the title complex, [Co(NCS)(2)(C(7)H(9)N)(2)(CH(3)OH)(2)], comprises of one Co(II) cation located on a centre of inversion, one thio­cyanate ligand, one methanol ligand and one 3,5-di­methyl­pyridine ligand. The Co(II) cation is octa­hedrally coordinated by two terminal N-bonding thio­cyanate anions, two methanol mol­ecules and two 3,5-di­methyl­pyridine ligands into a discrete complex. The complex mol­ecules are linked by inter­molecular O—H⋯S hydrogen bonding into chains that elongate in the direction parallel to the b axis.
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spelling pubmed-51376182016-12-15 Crystal structure of bis­(3,5-di­methyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II) Suckert, Stefan Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title complex, [Co(NCS)(2)(C(7)H(9)N)(2)(CH(3)OH)(2)], comprises of one Co(II) cation located on a centre of inversion, one thio­cyanate ligand, one methanol ligand and one 3,5-di­methyl­pyridine ligand. The Co(II) cation is octa­hedrally coordinated by two terminal N-bonding thio­cyanate anions, two methanol mol­ecules and two 3,5-di­methyl­pyridine ligands into a discrete complex. The complex mol­ecules are linked by inter­molecular O—H⋯S hydrogen bonding into chains that elongate in the direction parallel to the b axis. International Union of Crystallography 2016-11-18 /pmc/articles/PMC5137618/ /pubmed/27980840 http://dx.doi.org/10.1107/S2056989016018326 Text en © Suckert et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Suckert, Stefan
Jess, Inke
Näther, Christian
Crystal structure of bis­(3,5-di­methyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title Crystal structure of bis­(3,5-di­methyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title_full Crystal structure of bis­(3,5-di­methyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title_fullStr Crystal structure of bis­(3,5-di­methyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title_full_unstemmed Crystal structure of bis­(3,5-di­methyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title_short Crystal structure of bis­(3,5-di­methyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)
title_sort crystal structure of bis­(3,5-di­methyl­pyridine-κn)bis­(methanol-κo)bis­(thio­cyanato-κn)cobalt(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137618/
https://www.ncbi.nlm.nih.gov/pubmed/27980840
http://dx.doi.org/10.1107/S2056989016018326
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