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Crystal structure of (aceto­nitrile-κN)iodido­(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri­methyl­phen­yl)imino]ethyl}­pyridine-κ(2) N,N′)copper(I)

In the mononuclear title complex, [CuI(C(2)H(3)N)(C(26)H(24)N(2))], the Cu(I) ion has a distorted tetra­hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri­methyl­phen­yl)imino]­pyridine ligand, one N atom of an aceto­nitrile ligand and one iodi...

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Detalles Bibliográficos
Autores principales: Al-Najjar, Nada, Solan, Gregory A., Singh, Kuldip
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137624/
https://www.ncbi.nlm.nih.gov/pubmed/27980846
http://dx.doi.org/10.1107/S2056989016018685
Descripción
Sumario:In the mononuclear title complex, [CuI(C(2)H(3)N)(C(26)H(24)N(2))], the Cu(I) ion has a distorted tetra­hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri­methyl­phen­yl)imino]­pyridine ligand, one N atom of an aceto­nitrile ligand and one iodide ligand. Within the complex, there are weak intra­molecular C—H⋯N hydrogen bonds, while weak inter­molecular C—H⋯I inter­actions between complex mol­ecules, help to facilitate a three-dimensional network.