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Crystal structure of (acetonitrile-κN)iodido(2-(naphthalen-1-yl)-6-{1-[(2,4,6-trimethylphenyl)imino]ethyl}pyridine-κ(2) N,N′)copper(I)
In the mononuclear title complex, [CuI(C(2)H(3)N)(C(26)H(24)N(2))], the Cu(I) ion has a distorted tetrahedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-trimethylphenyl)imino]pyridine ligand, one N atom of an acetonitrile ligand and one iodi...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137624/ https://www.ncbi.nlm.nih.gov/pubmed/27980846 http://dx.doi.org/10.1107/S2056989016018685 |
Sumario: | In the mononuclear title complex, [CuI(C(2)H(3)N)(C(26)H(24)N(2))], the Cu(I) ion has a distorted tetrahedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-trimethylphenyl)imino]pyridine ligand, one N atom of an acetonitrile ligand and one iodide ligand. Within the complex, there are weak intramolecular C—H⋯N hydrogen bonds, while weak intermolecular C—H⋯I interactions between complex molecules, help to facilitate a three-dimensional network. |
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