Crystal structure of [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), a compound showing argentophilic inter­actions

Bis[triamminesilver(I)] bis­[diamminesilver(I)] hexa­fluorido­stannate(IV) difluoride, [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), was obtained in the form of colourless crystals from the reaction of CsAgSnF(7) in anhydrous ammonia. Two different ammine complexes of silver(I) are present in the structure, i.e. a linear diammine and a T-shaped triammine complex. The ammine silver(I) complexes show Ag⋯Ag distances in the range of argentophilic inter­actions. In the crystal, several N—H⋯F hydrogen bonds are present between the complex cations and the SbF(6) (−) and F(−) anions, leading to the formation of a three-dimensional network.