Crystal structure of [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), a compound showing argentophilic inter­actions

Bis[triamminesilver(I)] bis­[diamminesilver(I)] hexa­fluorido­stannate(IV) difluoride, [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), was obtained in the form of colourless crystals from the reaction of CsAgSnF(7) in anhydrous ammonia. Two different ammine complexes of silver(I) are present in the...

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Autores principales: Kraus, Florian, Fichtl, Matthias, Baer, Sebastian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137628/
https://www.ncbi.nlm.nih.gov/pubmed/27980850
http://dx.doi.org/10.1107/S2056989016019010
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author Kraus, Florian
Fichtl, Matthias
Baer, Sebastian
author_facet Kraus, Florian
Fichtl, Matthias
Baer, Sebastian
author_sort Kraus, Florian
collection PubMed
description Bis[triamminesilver(I)] bis­[diamminesilver(I)] hexa­fluorido­stannate(IV) difluoride, [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), was obtained in the form of colourless crystals from the reaction of CsAgSnF(7) in anhydrous ammonia. Two different ammine complexes of silver(I) are present in the structure, i.e. a linear diammine and a T-shaped triammine complex. The ammine silver(I) complexes show Ag⋯Ag distances in the range of argentophilic inter­actions. In the crystal, several N—H⋯F hydrogen bonds are present between the complex cations and the SbF(6) (−) and F(−) anions, leading to the formation of a three-dimensional network.
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spelling pubmed-51376282016-12-15 Crystal structure of [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), a compound showing argentophilic inter­actions Kraus, Florian Fichtl, Matthias Baer, Sebastian Acta Crystallogr E Crystallogr Commun Research Communications Bis[triamminesilver(I)] bis­[diamminesilver(I)] hexa­fluorido­stannate(IV) difluoride, [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), was obtained in the form of colourless crystals from the reaction of CsAgSnF(7) in anhydrous ammonia. Two different ammine complexes of silver(I) are present in the structure, i.e. a linear diammine and a T-shaped triammine complex. The ammine silver(I) complexes show Ag⋯Ag distances in the range of argentophilic inter­actions. In the crystal, several N—H⋯F hydrogen bonds are present between the complex cations and the SbF(6) (−) and F(−) anions, leading to the formation of a three-dimensional network. International Union of Crystallography 2016-11-29 /pmc/articles/PMC5137628/ /pubmed/27980850 http://dx.doi.org/10.1107/S2056989016019010 Text en © Kraus et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Kraus, Florian
Fichtl, Matthias
Baer, Sebastian
Crystal structure of [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), a compound showing argentophilic inter­actions
title Crystal structure of [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), a compound showing argentophilic inter­actions
title_full Crystal structure of [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), a compound showing argentophilic inter­actions
title_fullStr Crystal structure of [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), a compound showing argentophilic inter­actions
title_full_unstemmed Crystal structure of [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), a compound showing argentophilic inter­actions
title_short Crystal structure of [Ag(NH(3))(3)](2)[Ag(NH(3))(2)](2)[SnF(6)]F(2), a compound showing argentophilic inter­actions
title_sort crystal structure of [ag(nh(3))(3)](2)[ag(nh(3))(2)](2)[snf(6)]f(2), a compound showing argentophilic inter­actions
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137628/
https://www.ncbi.nlm.nih.gov/pubmed/27980850
http://dx.doi.org/10.1107/S2056989016019010
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