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Crystal structure of trans-cyclohexane-1,2-diammonium chromate(VI) from synchrotron X-ray diffraction data
The structure of the title hybrid compound, (C(6)H(16)N(2))[CrO(4)], has been determined from synchrotron data. The organic cation adopts a chair conformation. The inorganic CrO(4) (2−) anion is slightly distorted owing to its involvement in N—H⋯O hydrogen-bonding interactions with neighbouring tra...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2016
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137631/ https://www.ncbi.nlm.nih.gov/pubmed/27980853 http://dx.doi.org/10.1107/S2056989016019009 |
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author | Moon, Dohyun Choi, Jong-Ha |
author_facet | Moon, Dohyun Choi, Jong-Ha |
author_sort | Moon, Dohyun |
collection | PubMed |
description | The structure of the title hybrid compound, (C(6)H(16)N(2))[CrO(4)], has been determined from synchrotron data. The organic cation adopts a chair conformation. The inorganic CrO(4) (2−) anion is slightly distorted owing to its involvement in N—H⋯O hydrogen-bonding interactions with neighbouring trans-cyclohexane-1,2-diammonium cations, whereby the two Cr—O bonds to the O atoms acting as acceptor atoms for two hydrogen bonds are slightly longer than the other two Cr—O bonds for which only one acceptor interaction per O atom is observed. In the crystal, cations and anions are packed into layers parallel to (001), held together through the aforementioned N—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-5137631 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-51376312016-12-15 Crystal structure of trans-cyclohexane-1,2-diammonium chromate(VI) from synchrotron X-ray diffraction data Moon, Dohyun Choi, Jong-Ha Acta Crystallogr E Crystallogr Commun Research Communications The structure of the title hybrid compound, (C(6)H(16)N(2))[CrO(4)], has been determined from synchrotron data. The organic cation adopts a chair conformation. The inorganic CrO(4) (2−) anion is slightly distorted owing to its involvement in N—H⋯O hydrogen-bonding interactions with neighbouring trans-cyclohexane-1,2-diammonium cations, whereby the two Cr—O bonds to the O atoms acting as acceptor atoms for two hydrogen bonds are slightly longer than the other two Cr—O bonds for which only one acceptor interaction per O atom is observed. In the crystal, cations and anions are packed into layers parallel to (001), held together through the aforementioned N—H⋯O hydrogen bonds. International Union of Crystallography 2016-11-30 /pmc/articles/PMC5137631/ /pubmed/27980853 http://dx.doi.org/10.1107/S2056989016019009 Text en © Moon and Choi 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Moon, Dohyun Choi, Jong-Ha Crystal structure of trans-cyclohexane-1,2-diammonium chromate(VI) from synchrotron X-ray diffraction data |
title | Crystal structure of trans-cyclohexane-1,2-diammonium chromate(VI) from synchrotron X-ray diffraction data |
title_full | Crystal structure of trans-cyclohexane-1,2-diammonium chromate(VI) from synchrotron X-ray diffraction data |
title_fullStr | Crystal structure of trans-cyclohexane-1,2-diammonium chromate(VI) from synchrotron X-ray diffraction data |
title_full_unstemmed | Crystal structure of trans-cyclohexane-1,2-diammonium chromate(VI) from synchrotron X-ray diffraction data |
title_short | Crystal structure of trans-cyclohexane-1,2-diammonium chromate(VI) from synchrotron X-ray diffraction data |
title_sort | crystal structure of trans-cyclohexane-1,2-diammonium chromate(vi) from synchrotron x-ray diffraction data |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137631/ https://www.ncbi.nlm.nih.gov/pubmed/27980853 http://dx.doi.org/10.1107/S2056989016019009 |
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