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Crystal structure of trans-cyclo­hexane-1,2-di­ammonium chromate(VI) from synchrotron X-ray diffraction data

The structure of the title hybrid compound, (C(6)H(16)N(2))[CrO(4)], has been determined from synchrotron data. The organic cation adopts a chair conformation. The inorganic CrO(4) (2−) anion is slightly distorted owing to its involvement in N—H⋯O hydrogen-bonding inter­actions with neighbouring tra...

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Autores principales: Moon, Dohyun, Choi, Jong-Ha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137631/
https://www.ncbi.nlm.nih.gov/pubmed/27980853
http://dx.doi.org/10.1107/S2056989016019009
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author Moon, Dohyun
Choi, Jong-Ha
author_facet Moon, Dohyun
Choi, Jong-Ha
author_sort Moon, Dohyun
collection PubMed
description The structure of the title hybrid compound, (C(6)H(16)N(2))[CrO(4)], has been determined from synchrotron data. The organic cation adopts a chair conformation. The inorganic CrO(4) (2−) anion is slightly distorted owing to its involvement in N—H⋯O hydrogen-bonding inter­actions with neighbouring trans-cyclo­hexane-1,2-di­ammonium cations, whereby the two Cr—O bonds to the O atoms acting as acceptor atoms for two hydrogen bonds are slightly longer than the other two Cr—O bonds for which only one acceptor inter­action per O atom is observed. In the crystal, cations and anions are packed into layers parallel to (001), held together through the aforementioned N—H⋯O hydrogen bonds.
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spelling pubmed-51376312016-12-15 Crystal structure of trans-cyclo­hexane-1,2-di­ammonium chromate(VI) from synchrotron X-ray diffraction data Moon, Dohyun Choi, Jong-Ha Acta Crystallogr E Crystallogr Commun Research Communications The structure of the title hybrid compound, (C(6)H(16)N(2))[CrO(4)], has been determined from synchrotron data. The organic cation adopts a chair conformation. The inorganic CrO(4) (2−) anion is slightly distorted owing to its involvement in N—H⋯O hydrogen-bonding inter­actions with neighbouring trans-cyclo­hexane-1,2-di­ammonium cations, whereby the two Cr—O bonds to the O atoms acting as acceptor atoms for two hydrogen bonds are slightly longer than the other two Cr—O bonds for which only one acceptor inter­action per O atom is observed. In the crystal, cations and anions are packed into layers parallel to (001), held together through the aforementioned N—H⋯O hydrogen bonds. International Union of Crystallography 2016-11-30 /pmc/articles/PMC5137631/ /pubmed/27980853 http://dx.doi.org/10.1107/S2056989016019009 Text en © Moon and Choi 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Moon, Dohyun
Choi, Jong-Ha
Crystal structure of trans-cyclo­hexane-1,2-di­ammonium chromate(VI) from synchrotron X-ray diffraction data
title Crystal structure of trans-cyclo­hexane-1,2-di­ammonium chromate(VI) from synchrotron X-ray diffraction data
title_full Crystal structure of trans-cyclo­hexane-1,2-di­ammonium chromate(VI) from synchrotron X-ray diffraction data
title_fullStr Crystal structure of trans-cyclo­hexane-1,2-di­ammonium chromate(VI) from synchrotron X-ray diffraction data
title_full_unstemmed Crystal structure of trans-cyclo­hexane-1,2-di­ammonium chromate(VI) from synchrotron X-ray diffraction data
title_short Crystal structure of trans-cyclo­hexane-1,2-di­ammonium chromate(VI) from synchrotron X-ray diffraction data
title_sort crystal structure of trans-cyclo­hexane-1,2-di­ammonium chromate(vi) from synchrotron x-ray diffraction data
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137631/
https://www.ncbi.nlm.nih.gov/pubmed/27980853
http://dx.doi.org/10.1107/S2056989016019009
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