1,4-Dihydropyridines as Alkyl Radical Precursors: Introducing the Aldehyde Feedstock to Nickel/Photoredox Dual Catalysis

[Image: see text] A Ni/photoredox dual catalytic cross-coupling is disclosed in which a diverse range of (hetero)aryl bromides are used as electrophiles, with 1,4-dihydropyridines serving as precursors to C(sp)(3)-centered alkyl radical coupling partners. The reported method is characterized by its...

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Detalles Bibliográficos
Autores principales: Gutiérrez-Bonet, Álvaro, Tellis, John C., Matsui, Jennifer K., Vara, Brandon A., Molander, Gary A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5152669/
https://www.ncbi.nlm.nih.gov/pubmed/27990318
http://dx.doi.org/10.1021/acscatal.6b02786

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5152669/
https://www.ncbi.nlm.nih.gov/pubmed/27990318
http://dx.doi.org/10.1021/acscatal.6b02786

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