Preparation of NASICON-Type Nanosized Solid Electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) by Evaporation-Induced Self-Assembly for Lithium-Ion Battery

A simple and practicable evaporation-induced self-assembly (EISA) method is introduced for the first time to prepare nanosized solid electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) (LATP) for all-solid-state lithium-ion batteries. A pure Na(+) super ion conductor (NASICON) phase is confirmed by X-ray di...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Xingang, Fu, Ju, Zhang, Chuhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2016
Materias:
Nano Express
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5159412/
https://www.ncbi.nlm.nih.gov/pubmed/27981524
http://dx.doi.org/10.1186/s11671-016-1768-z
_version_ 1782481765540036608
author Liu, Xingang
Fu, Ju
Zhang, Chuhong
author_facet Liu, Xingang
Fu, Ju
Zhang, Chuhong
author_sort Liu, Xingang
collection PubMed
description A simple and practicable evaporation-induced self-assembly (EISA) method is introduced for the first time to prepare nanosized solid electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) (LATP) for all-solid-state lithium-ion batteries. A pure Na(+) super ion conductor (NASICON) phase is confirmed by X-ray diffraction (XRD) analysis, and its primary particle size is down to 70 nm by optimizing evaporation rate of the solvent. Excellent room temperature bulk and total lithium-ion conductivities of 2.09 × 10(−3) S cm(−1) and 3.63 × 10(−4) S cm(−1) are obtained, with an ion-hopping activation energy as low as 0.286 eV.
format Online
Article
Text
id pubmed-5159412
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher Springer US
record_format MEDLINE/PubMed
spelling pubmed-51594122017-01-03 Preparation of NASICON-Type Nanosized Solid Electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) by Evaporation-Induced Self-Assembly for Lithium-Ion Battery Liu, Xingang Fu, Ju Zhang, Chuhong Nanoscale Res Lett Nano Express A simple and practicable evaporation-induced self-assembly (EISA) method is introduced for the first time to prepare nanosized solid electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) (LATP) for all-solid-state lithium-ion batteries. A pure Na(+) super ion conductor (NASICON) phase is confirmed by X-ray diffraction (XRD) analysis, and its primary particle size is down to 70 nm by optimizing evaporation rate of the solvent. Excellent room temperature bulk and total lithium-ion conductivities of 2.09 × 10(−3) S cm(−1) and 3.63 × 10(−4) S cm(−1) are obtained, with an ion-hopping activation energy as low as 0.286 eV. Springer US 2016-12-15 /pmc/articles/PMC5159412/ /pubmed/27981524 http://dx.doi.org/10.1186/s11671-016-1768-z Text en © The Author(s). 2016 Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
spellingShingle Nano Express
Liu, Xingang
Fu, Ju
Zhang, Chuhong
Preparation of NASICON-Type Nanosized Solid Electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) by Evaporation-Induced Self-Assembly for Lithium-Ion Battery
title Preparation of NASICON-Type Nanosized Solid Electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) by Evaporation-Induced Self-Assembly for Lithium-Ion Battery
title_full Preparation of NASICON-Type Nanosized Solid Electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) by Evaporation-Induced Self-Assembly for Lithium-Ion Battery
title_fullStr Preparation of NASICON-Type Nanosized Solid Electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) by Evaporation-Induced Self-Assembly for Lithium-Ion Battery
title_full_unstemmed Preparation of NASICON-Type Nanosized Solid Electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) by Evaporation-Induced Self-Assembly for Lithium-Ion Battery
title_short Preparation of NASICON-Type Nanosized Solid Electrolyte Li(1.4)Al(0.4)Ti(1.6)(PO(4))(3) by Evaporation-Induced Self-Assembly for Lithium-Ion Battery
title_sort preparation of nasicon-type nanosized solid electrolyte li(1.4)al(0.4)ti(1.6)(po(4))(3) by evaporation-induced self-assembly for lithium-ion battery
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5159412/
https://www.ncbi.nlm.nih.gov/pubmed/27981524
http://dx.doi.org/10.1186/s11671-016-1768-z
work_keys_str_mv AT liuxingang preparationofnasicontypenanosizedsolidelectrolyteli14al04ti16po43byevaporationinducedselfassemblyforlithiumionbattery
AT fuju preparationofnasicontypenanosizedsolidelectrolyteli14al04ti16po43byevaporationinducedselfassemblyforlithiumionbattery
AT zhangchuhong preparationofnasicontypenanosizedsolidelectrolyteli14al04ti16po43byevaporationinducedselfassemblyforlithiumionbattery

Ejemplares similares