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Lewis‐Acid‐assisted Hydrogen Atom Transfer to Manganese(V)‐Oxo Corrole through Valence Tautomerization
The kinetics of formation of the valence tautomers (tpfc(⋅))Mn(IV)(O−LA)](n+) [where LA=Zn(II), Ca(II), Sc(III), Yb(III), B(C(6)F(5))(3), and trifluoroacetic acid (TFA); tpfc=5,10,15‐tris(pentafluorophenyl) corrole] from (tpfc)Mn(V)(O) were followed by UV/Vis spectroscopy, giving second‐order rate c...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5167333/ https://www.ncbi.nlm.nih.gov/pubmed/28032019 http://dx.doi.org/10.1002/open.201600117 |