Facile Preparation of Chloride‐Conducting Membranes: First Step towards a Room‐Temperature Solid‐State Chloride‐Ion Battery

Three types of chloride‐conducting membranes based on polyvinyl chloride, commercial gelatin, and polyvinyldifluoride‐hexafluoropolymer are introduced in this report. The polymers are mixed with chloride‐containing salts, such as tetrabutylammonium chloride, and cast to form membranes. We studied th...

Descripción completa

Detalles Bibliográficos
Autores principales: Gschwind, Fabienne, Steinle, Dominik, Sandbeck, Daniel, Schmidt, Celine, von Hauff, Elizabeth
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5167400/
https://www.ncbi.nlm.nih.gov/pubmed/28032020
http://dx.doi.org/10.1002/open.201600109
_version_ 1782483172883169280
author Gschwind, Fabienne
Steinle, Dominik
Sandbeck, Daniel
Schmidt, Celine
von Hauff, Elizabeth
author_facet Gschwind, Fabienne
Steinle, Dominik
Sandbeck, Daniel
Schmidt, Celine
von Hauff, Elizabeth
author_sort Gschwind, Fabienne
collection PubMed
description Three types of chloride‐conducting membranes based on polyvinyl chloride, commercial gelatin, and polyvinyldifluoride‐hexafluoropolymer are introduced in this report. The polymers are mixed with chloride‐containing salts, such as tetrabutylammonium chloride, and cast to form membranes. We studied the structural properties, thermal stability, and electrochemical response of the membranes to understand chloride migration and transport. Finally, the membranes are tested in a prototype solid‐state chloride‐ion battery setup. The feasibility of the membranes for their potential use in anion batteries is discussed.
format Online
Article
Text
id pubmed-5167400
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-51674002016-12-28 Facile Preparation of Chloride‐Conducting Membranes: First Step towards a Room‐Temperature Solid‐State Chloride‐Ion Battery Gschwind, Fabienne Steinle, Dominik Sandbeck, Daniel Schmidt, Celine von Hauff, Elizabeth ChemistryOpen Communications Three types of chloride‐conducting membranes based on polyvinyl chloride, commercial gelatin, and polyvinyldifluoride‐hexafluoropolymer are introduced in this report. The polymers are mixed with chloride‐containing salts, such as tetrabutylammonium chloride, and cast to form membranes. We studied the structural properties, thermal stability, and electrochemical response of the membranes to understand chloride migration and transport. Finally, the membranes are tested in a prototype solid‐state chloride‐ion battery setup. The feasibility of the membranes for their potential use in anion batteries is discussed. John Wiley and Sons Inc. 2016-11-25 /pmc/articles/PMC5167400/ /pubmed/28032020 http://dx.doi.org/10.1002/open.201600109 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs (http://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Gschwind, Fabienne
Steinle, Dominik
Sandbeck, Daniel
Schmidt, Celine
von Hauff, Elizabeth
Facile Preparation of Chloride‐Conducting Membranes: First Step towards a Room‐Temperature Solid‐State Chloride‐Ion Battery
title Facile Preparation of Chloride‐Conducting Membranes: First Step towards a Room‐Temperature Solid‐State Chloride‐Ion Battery
title_full Facile Preparation of Chloride‐Conducting Membranes: First Step towards a Room‐Temperature Solid‐State Chloride‐Ion Battery
title_fullStr Facile Preparation of Chloride‐Conducting Membranes: First Step towards a Room‐Temperature Solid‐State Chloride‐Ion Battery
title_full_unstemmed Facile Preparation of Chloride‐Conducting Membranes: First Step towards a Room‐Temperature Solid‐State Chloride‐Ion Battery
title_short Facile Preparation of Chloride‐Conducting Membranes: First Step towards a Room‐Temperature Solid‐State Chloride‐Ion Battery
title_sort facile preparation of chloride‐conducting membranes: first step towards a room‐temperature solid‐state chloride‐ion battery
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5167400/
https://www.ncbi.nlm.nih.gov/pubmed/28032020
http://dx.doi.org/10.1002/open.201600109
work_keys_str_mv AT gschwindfabienne facilepreparationofchlorideconductingmembranesfirststeptowardsaroomtemperaturesolidstatechlorideionbattery
AT steinledominik facilepreparationofchlorideconductingmembranesfirststeptowardsaroomtemperaturesolidstatechlorideionbattery
AT sandbeckdaniel facilepreparationofchlorideconductingmembranesfirststeptowardsaroomtemperaturesolidstatechlorideionbattery
AT schmidtceline facilepreparationofchlorideconductingmembranesfirststeptowardsaroomtemperaturesolidstatechlorideionbattery
AT vonhauffelizabeth facilepreparationofchlorideconductingmembranesfirststeptowardsaroomtemperaturesolidstatechlorideionbattery

Ejemplares similares