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Arene guest selectivity and pore flexibility in a metal–organic framework with semi-fluorinated channel walls
A metal–organic framework (MOF) with one-dimensional channels of approximately hexagonal cross-section [Ag(2)(O(2)CCF(2)CF(2)CO(2))(TMP)] 1 (TMP =2,3,5,6-tetramethylpyrazine) has been synthesized with MeOH filling the channels in its as-synthesized form as [Ag(2)(O(2)CCF(2)CF(2)CO(2))(TMP)]·n(MeOH)...
Autores principales: | Smith, Rebecca, Vitórica-Yrezábal, Iñigo J., Hill, Adrian, Brammer, Lee |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5179934/ https://www.ncbi.nlm.nih.gov/pubmed/27895259 http://dx.doi.org/10.1098/rsta.2016.0031 |
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