Iridium Cyclooctene Complex That Forms a Hyperpolarization Transfer Catalyst before Converting to a Binuclear C–H Bond Activation Product Responsible for Hydrogen Isotope Exchange

[Image: see text] [IrCl(COE)(2)](2) (1) reacts with pyridine (py) and H(2) to form crystallographically characterized IrCl(H)(2)(COE)(py)(2) (2). 2 undergoes py loss to form 16-electron IrCl(H)(2)(COE)(py) (3), with equivalent hydride ligands. When this reaction is studied with parahydrogen, 1 effic...

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Detalles Bibliográficos
Autores principales: Iali, Wissam, Green, Gary G. R., Hart, Sam J., Whitwood, Adrian C., Duckett, Simon B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5193467/
https://www.ncbi.nlm.nih.gov/pubmed/27934314
http://dx.doi.org/10.1021/acs.inorgchem.6b02560

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5193467/
https://www.ncbi.nlm.nih.gov/pubmed/27934314
http://dx.doi.org/10.1021/acs.inorgchem.6b02560

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