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Iridium Cyclooctene Complex That Forms a Hyperpolarization Transfer Catalyst before Converting to a Binuclear C–H Bond Activation Product Responsible for Hydrogen Isotope Exchange
[Image: see text] [IrCl(COE)(2)](2) (1) reacts with pyridine (py) and H(2) to form crystallographically characterized IrCl(H)(2)(COE)(py)(2) (2). 2 undergoes py loss to form 16-electron IrCl(H)(2)(COE)(py) (3), with equivalent hydride ligands. When this reaction is studied with parahydrogen, 1 effic...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5193467/ https://www.ncbi.nlm.nih.gov/pubmed/27934314 http://dx.doi.org/10.1021/acs.inorgchem.6b02560 |