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Crystal structure of bis{μ-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-κ(4) O,N,N′,O′}bis[dibutyltin(IV)]
Condensation of 8-hydroxyquinoline-2-carbaldehyde with 2-aminophenol gave the (E)-2-[(2-hydroxyphenylimino)methyl]quinolin-8-ol derivative that reacted with di-n-butyltin oxide with release of H(2)O to yield the chelate title complex, [Sn(2)(C(4)H(9))(4)(C(16)H(10)N(2)O(2))(2)]. The compoun...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209758/ https://www.ncbi.nlm.nih.gov/pubmed/28083122 http://dx.doi.org/10.1107/S2056989016018867 |
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author | Carlos, Camacho-Camacho Naytzé, Ortiz-Pastrana Ariadna, Garza-Ortiz Irma, Rojas-Oviedo |
author_facet | Carlos, Camacho-Camacho Naytzé, Ortiz-Pastrana Ariadna, Garza-Ortiz Irma, Rojas-Oviedo |
author_sort | Carlos, Camacho-Camacho |
collection | PubMed |
description | Condensation of 8-hydroxyquinoline-2-carbaldehyde with 2-aminophenol gave the (E)-2-[(2-hydroxyphenylimino)methyl]quinolin-8-ol derivative that reacted with di-n-butyltin oxide with release of H(2)O to yield the chelate title complex, [Sn(2)(C(4)H(9))(4)(C(16)H(10)N(2)O(2))(2)]. The compound crystallizes in the triclinic space group P-1, with two independent centrosymmetric dimers in the unit cell. Each features a typical pincer-type structure where the dianionic ligand is tetradentate, coordinating to the central tin atom through both phenolate oxygen atoms, as well as through the quinoline and imine N atoms. Each metal atom adopts a distorted pentagonal–bipyramidal SnC(2)N(2)O(3) coordination arising from the N,N′,O,O′-tetradentate deprotonated Schiff base, one bridging phenolate O atom of the neighbouring ligand and two butyl groups in the axial sites. |
format | Online Article Text |
id | pubmed-5209758 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-52097582017-01-12 Crystal structure of bis{μ-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-κ(4) O,N,N′,O′}bis[dibutyltin(IV)] Carlos, Camacho-Camacho Naytzé, Ortiz-Pastrana Ariadna, Garza-Ortiz Irma, Rojas-Oviedo Acta Crystallogr E Crystallogr Commun Research Communications Condensation of 8-hydroxyquinoline-2-carbaldehyde with 2-aminophenol gave the (E)-2-[(2-hydroxyphenylimino)methyl]quinolin-8-ol derivative that reacted with di-n-butyltin oxide with release of H(2)O to yield the chelate title complex, [Sn(2)(C(4)H(9))(4)(C(16)H(10)N(2)O(2))(2)]. The compound crystallizes in the triclinic space group P-1, with two independent centrosymmetric dimers in the unit cell. Each features a typical pincer-type structure where the dianionic ligand is tetradentate, coordinating to the central tin atom through both phenolate oxygen atoms, as well as through the quinoline and imine N atoms. Each metal atom adopts a distorted pentagonal–bipyramidal SnC(2)N(2)O(3) coordination arising from the N,N′,O,O′-tetradentate deprotonated Schiff base, one bridging phenolate O atom of the neighbouring ligand and two butyl groups in the axial sites. International Union of Crystallography 2017-01-01 /pmc/articles/PMC5209758/ /pubmed/28083122 http://dx.doi.org/10.1107/S2056989016018867 Text en © Carlos et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Carlos, Camacho-Camacho Naytzé, Ortiz-Pastrana Ariadna, Garza-Ortiz Irma, Rojas-Oviedo Crystal structure of bis{μ-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-κ(4) O,N,N′,O′}bis[dibutyltin(IV)] |
title | Crystal structure of bis{μ-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-κ(4)
O,N,N′,O′}bis[dibutyltin(IV)] |
title_full | Crystal structure of bis{μ-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-κ(4)
O,N,N′,O′}bis[dibutyltin(IV)] |
title_fullStr | Crystal structure of bis{μ-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-κ(4)
O,N,N′,O′}bis[dibutyltin(IV)] |
title_full_unstemmed | Crystal structure of bis{μ-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-κ(4)
O,N,N′,O′}bis[dibutyltin(IV)] |
title_short | Crystal structure of bis{μ-(E)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-κ(4)
O,N,N′,O′}bis[dibutyltin(IV)] |
title_sort | crystal structure of bis{μ-(e)-2-[(2-oxidophenylimino)methyl]quinolin-8-olato-κ(4)
o,n,n′,o′}bis[dibutyltin(iv)] |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209758/ https://www.ncbi.nlm.nih.gov/pubmed/28083122 http://dx.doi.org/10.1107/S2056989016018867 |
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