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Crystal structure of bis{N′-[(E)-4-hydroxybenzylidene]pyridine-4-carbohydrazide-κN (1)}diiodidocadmium methanol disolvate
In the title compound, [Cd(C(13)H(11)IN(3)O(2))(2)]·2CH(3)OH, which crystallizes with Z = 4 in the space group Pbcn, the Cd(II) atom is located on a twofold rotation axis and coordinated by two I(−) anions and two N atoms from the pyridine rings of the two N′-[(E)-4-hydroxybenzylidene]pyridine-4-...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209764/ https://www.ncbi.nlm.nih.gov/pubmed/28083128 http://dx.doi.org/10.1107/S2056989016019575 |
Sumario: | In the title compound, [Cd(C(13)H(11)IN(3)O(2))(2)]·2CH(3)OH, which crystallizes with Z = 4 in the space group Pbcn, the Cd(II) atom is located on a twofold rotation axis and coordinated by two I(−) anions and two N atoms from the pyridine rings of the two N′-[(E)-4-hydroxybenzylidene]pyridine-4-carbohydrazide ligands. The geometry around the Cd(II) atom is distorted tetrahedral, with bond angles in the range 94.92 (11)–124.29 (2)°. The iodide anions undergo intermolecular hydrogen-bonding contacts with the C—H groups of the organic ligands of an adjacent complex molecule, generating a chain structure along the b axis. Furthermore, an extensive series of O—H⋯O, N—H⋯O and C—H⋯O hydrogen-bonding interactions involving both the complex molecules and the ethanol solvate molecules generate a three-dimensional network. |
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