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Crystal structure of bis­{N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide-κN (1)}di­iodidocadmium methanol disolvate

In the title compound, [Cd(C(13)H(11)IN(3)O(2))(2)]·2CH(3)OH, which crystallizes with Z = 4 in the space group Pbcn, the Cd(II) atom is located on a twofold rotation axis and coordinated by two I(−) anions and two N atoms from the pyridine rings of the two N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-...

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Autores principales: Afkhami, Farhad Akbari, Krautscheid, Harald, Atioğlu, Zeliha, Akkurt, Mehmet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209764/
https://www.ncbi.nlm.nih.gov/pubmed/28083128
http://dx.doi.org/10.1107/S2056989016019575
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author Afkhami, Farhad Akbari
Krautscheid, Harald
Atioğlu, Zeliha
Akkurt, Mehmet
author_facet Afkhami, Farhad Akbari
Krautscheid, Harald
Atioğlu, Zeliha
Akkurt, Mehmet
author_sort Afkhami, Farhad Akbari
collection PubMed
description In the title compound, [Cd(C(13)H(11)IN(3)O(2))(2)]·2CH(3)OH, which crystallizes with Z = 4 in the space group Pbcn, the Cd(II) atom is located on a twofold rotation axis and coordinated by two I(−) anions and two N atoms from the pyridine rings of the two N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide ligands. The geometry around the Cd(II) atom is distorted tetra­hedral, with bond angles in the range 94.92 (11)–124.29 (2)°. The iodide anions undergo inter­molecular hydrogen-bonding contacts with the C—H groups of the organic ligands of an adjacent complex mol­ecule, generating a chain structure along the b axis. Furthermore, an extensive series of O—H⋯O, N—H⋯O and C—H⋯O hydrogen-bonding inter­actions involving both the complex mol­ecules and the ethanol solvate mol­ecules generate a three-dimensional network.
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spelling pubmed-52097642017-01-12 Crystal structure of bis­{N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide-κN (1)}di­iodidocadmium methanol disolvate Afkhami, Farhad Akbari Krautscheid, Harald Atioğlu, Zeliha Akkurt, Mehmet Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Cd(C(13)H(11)IN(3)O(2))(2)]·2CH(3)OH, which crystallizes with Z = 4 in the space group Pbcn, the Cd(II) atom is located on a twofold rotation axis and coordinated by two I(−) anions and two N atoms from the pyridine rings of the two N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide ligands. The geometry around the Cd(II) atom is distorted tetra­hedral, with bond angles in the range 94.92 (11)–124.29 (2)°. The iodide anions undergo inter­molecular hydrogen-bonding contacts with the C—H groups of the organic ligands of an adjacent complex mol­ecule, generating a chain structure along the b axis. Furthermore, an extensive series of O—H⋯O, N—H⋯O and C—H⋯O hydrogen-bonding inter­actions involving both the complex mol­ecules and the ethanol solvate mol­ecules generate a three-dimensional network. International Union of Crystallography 2017-01-01 /pmc/articles/PMC5209764/ /pubmed/28083128 http://dx.doi.org/10.1107/S2056989016019575 Text en © Afkhami et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Afkhami, Farhad Akbari
Krautscheid, Harald
Atioğlu, Zeliha
Akkurt, Mehmet
Crystal structure of bis­{N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide-κN (1)}di­iodidocadmium methanol disolvate
title Crystal structure of bis­{N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide-κN (1)}di­iodidocadmium methanol disolvate
title_full Crystal structure of bis­{N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide-κN (1)}di­iodidocadmium methanol disolvate
title_fullStr Crystal structure of bis­{N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide-κN (1)}di­iodidocadmium methanol disolvate
title_full_unstemmed Crystal structure of bis­{N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide-κN (1)}di­iodidocadmium methanol disolvate
title_short Crystal structure of bis­{N′-[(E)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide-κN (1)}di­iodidocadmium methanol disolvate
title_sort crystal structure of bis­{n′-[(e)-4-hy­droxy­benzyl­idene]pyridine-4-carbohydrazide-κn (1)}di­iodidocadmium methanol disolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209764/
https://www.ncbi.nlm.nih.gov/pubmed/28083128
http://dx.doi.org/10.1107/S2056989016019575
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