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Crystal structure of (E)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol

The title compound, C(23)H(29)N(3)O, was synthesized from the condensation reaction of 8-hy­droxy­julolidine-9-carbaldehyde and N,N-diethyl-p-phenyl­enedi­amine. The hy­droxy group forms a intra­molecular hydrogen bond to the imine N atom and generates an S(6) ring motif. The conformation about the...

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Detalles Bibliográficos
Autores principales: Faizi, Md. Serajul Haque, Ahmad, Musheer, Kapshuk, Anatoly A., Golenya, Irina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209767/
https://www.ncbi.nlm.nih.gov/pubmed/28083131
http://dx.doi.org/10.1107/S2056989016019733
Descripción
Sumario:The title compound, C(23)H(29)N(3)O, was synthesized from the condensation reaction of 8-hy­droxy­julolidine-9-carbaldehyde and N,N-diethyl-p-phenyl­enedi­amine. The hy­droxy group forms a intra­molecular hydrogen bond to the imine N atom and generates an S(6) ring motif. The conformation about the C=N bond is E, and the aromatic ring of the julolidine moiety is inclined to the benzene ring by 3.74 (14)°. One of the fused non-aromatic rings of the julolidine moiety adopts an envelope conformation and the other has a screw-boat conformation. In the crystal, mol­ecules are linked by C—H⋯π inter­actions involving the aromatic julolidine ring, forming slabs parallel to the bc plane. The tricyclic fragment of the julolidine ring and the azomethine C=N bond are disordered over two sets of sites with a refined occupancy ratio of 0.773 (3):0.227 (3).