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Crystal structure of (E)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol

The title compound, C(23)H(29)N(3)O, was synthesized from the condensation reaction of 8-hy­droxy­julolidine-9-carbaldehyde and N,N-diethyl-p-phenyl­enedi­amine. The hy­droxy group forms a intra­molecular hydrogen bond to the imine N atom and generates an S(6) ring motif. The conformation about the...

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Autores principales: Faizi, Md. Serajul Haque, Ahmad, Musheer, Kapshuk, Anatoly A., Golenya, Irina A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209767/
https://www.ncbi.nlm.nih.gov/pubmed/28083131
http://dx.doi.org/10.1107/S2056989016019733
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author Faizi, Md. Serajul Haque
Ahmad, Musheer
Kapshuk, Anatoly A.
Golenya, Irina A.
author_facet Faizi, Md. Serajul Haque
Ahmad, Musheer
Kapshuk, Anatoly A.
Golenya, Irina A.
author_sort Faizi, Md. Serajul Haque
collection PubMed
description The title compound, C(23)H(29)N(3)O, was synthesized from the condensation reaction of 8-hy­droxy­julolidine-9-carbaldehyde and N,N-diethyl-p-phenyl­enedi­amine. The hy­droxy group forms a intra­molecular hydrogen bond to the imine N atom and generates an S(6) ring motif. The conformation about the C=N bond is E, and the aromatic ring of the julolidine moiety is inclined to the benzene ring by 3.74 (14)°. One of the fused non-aromatic rings of the julolidine moiety adopts an envelope conformation and the other has a screw-boat conformation. In the crystal, mol­ecules are linked by C—H⋯π inter­actions involving the aromatic julolidine ring, forming slabs parallel to the bc plane. The tricyclic fragment of the julolidine ring and the azomethine C=N bond are disordered over two sets of sites with a refined occupancy ratio of 0.773 (3):0.227 (3).
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spelling pubmed-52097672017-01-12 Crystal structure of (E)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol Faizi, Md. Serajul Haque Ahmad, Musheer Kapshuk, Anatoly A. Golenya, Irina A. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(23)H(29)N(3)O, was synthesized from the condensation reaction of 8-hy­droxy­julolidine-9-carbaldehyde and N,N-diethyl-p-phenyl­enedi­amine. The hy­droxy group forms a intra­molecular hydrogen bond to the imine N atom and generates an S(6) ring motif. The conformation about the C=N bond is E, and the aromatic ring of the julolidine moiety is inclined to the benzene ring by 3.74 (14)°. One of the fused non-aromatic rings of the julolidine moiety adopts an envelope conformation and the other has a screw-boat conformation. In the crystal, mol­ecules are linked by C—H⋯π inter­actions involving the aromatic julolidine ring, forming slabs parallel to the bc plane. The tricyclic fragment of the julolidine ring and the azomethine C=N bond are disordered over two sets of sites with a refined occupancy ratio of 0.773 (3):0.227 (3). International Union of Crystallography 2017-01-01 /pmc/articles/PMC5209767/ /pubmed/28083131 http://dx.doi.org/10.1107/S2056989016019733 Text en © Faizi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Faizi, Md. Serajul Haque
Ahmad, Musheer
Kapshuk, Anatoly A.
Golenya, Irina A.
Crystal structure of (E)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol
title Crystal structure of (E)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol
title_full Crystal structure of (E)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol
title_fullStr Crystal structure of (E)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol
title_full_unstemmed Crystal structure of (E)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol
title_short Crystal structure of (E)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1H,5H-pyrido[3,2,1-ij]quinolin-8-ol
title_sort crystal structure of (e)-9-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)-2,3,6,7-tetra­hydro-1h,5h-pyrido[3,2,1-ij]quinolin-8-ol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209767/
https://www.ncbi.nlm.nih.gov/pubmed/28083131
http://dx.doi.org/10.1107/S2056989016019733
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