Crystal structure of chlorido­[1-(4-nitro­phen­yl)thio­urea-κS]bis­(tri­phenyl­phosphane-κP)copper(I)

The mononuclear mixed-ligand title complex, [CuCl(C(7)H(7)N(3)O(2)S)(C(18)H(15)P)(2)], displays a distorted tetra­hedral coordination sphere around the Cu(I) atom, with two P atoms from two tri­phenyl­phosphane mol­ecules, one terminal S atom from a 1-(4-nitro­phen­yl)thio­urea mol­ecule and a chloride ion as ligands. An intra­molecular N—H⋯Cl hydrogen bond stabilizes the mol­ecular conformation [graph-set motif R (2) (2)(6)]. In the crystal, further N—H⋯Cl hydrogen bonds connect individual mol­ecules into zigzag chains parallel to [001]. The chains are linked by weak C—H⋯O hydrogen-bonding inter­actions into a three-dimensional network.