Crystal structure of 4-(4b,8a-di­hydro-9H-pyrido[3,4-b]indol-1-yl)-7-methyl-2H-chromen-2-one

The title compound, C(21)H(14)N(2)O(2), was prepared by Pictet–Spengler cyclization of tryptamine and 4-formyl coumarin. In the mol­ecule, the dihedral angle between the mean planes of the coumarin and β-carboline ring systems is 63.8 (2)°. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bo...

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Autores principales: Samundeeswari, S., Kulkarni, Manohar V., Anil Kumar, G. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209772/
https://www.ncbi.nlm.nih.gov/pubmed/28083136
http://dx.doi.org/10.1107/S2056989016019769
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author Samundeeswari, S.
Kulkarni, Manohar V.
Anil Kumar, G. N.
author_facet Samundeeswari, S.
Kulkarni, Manohar V.
Anil Kumar, G. N.
author_sort Samundeeswari, S.
collection PubMed
description The title compound, C(21)H(14)N(2)O(2), was prepared by Pictet–Spengler cyclization of tryptamine and 4-formyl coumarin. In the mol­ecule, the dihedral angle between the mean planes of the coumarin and β-carboline ring systems is 63.8 (2)°. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming chains along the b-axis direction. Within the chains, there are a number of offset π–π inter­actions present [shortest inter­centroid distance = 3.457 (2) Å].
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spelling pubmed-52097722017-01-12 Crystal structure of 4-(4b,8a-di­hydro-9H-pyrido[3,4-b]indol-1-yl)-7-methyl-2H-chromen-2-one Samundeeswari, S. Kulkarni, Manohar V. Anil Kumar, G. N. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(21)H(14)N(2)O(2), was prepared by Pictet–Spengler cyclization of tryptamine and 4-formyl coumarin. In the mol­ecule, the dihedral angle between the mean planes of the coumarin and β-carboline ring systems is 63.8 (2)°. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming chains along the b-axis direction. Within the chains, there are a number of offset π–π inter­actions present [shortest inter­centroid distance = 3.457 (2) Å]. International Union of Crystallography 2017-01-01 /pmc/articles/PMC5209772/ /pubmed/28083136 http://dx.doi.org/10.1107/S2056989016019769 Text en © Samundeeswari et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Samundeeswari, S.
Kulkarni, Manohar V.
Anil Kumar, G. N.
Crystal structure of 4-(4b,8a-di­hydro-9H-pyrido[3,4-b]indol-1-yl)-7-methyl-2H-chromen-2-one
title Crystal structure of 4-(4b,8a-di­hydro-9H-pyrido[3,4-b]indol-1-yl)-7-methyl-2H-chromen-2-one
title_full Crystal structure of 4-(4b,8a-di­hydro-9H-pyrido[3,4-b]indol-1-yl)-7-methyl-2H-chromen-2-one
title_fullStr Crystal structure of 4-(4b,8a-di­hydro-9H-pyrido[3,4-b]indol-1-yl)-7-methyl-2H-chromen-2-one
title_full_unstemmed Crystal structure of 4-(4b,8a-di­hydro-9H-pyrido[3,4-b]indol-1-yl)-7-methyl-2H-chromen-2-one
title_short Crystal structure of 4-(4b,8a-di­hydro-9H-pyrido[3,4-b]indol-1-yl)-7-methyl-2H-chromen-2-one
title_sort crystal structure of 4-(4b,8a-di­hydro-9h-pyrido[3,4-b]indol-1-yl)-7-methyl-2h-chromen-2-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209772/
https://www.ncbi.nlm.nih.gov/pubmed/28083136
http://dx.doi.org/10.1107/S2056989016019769
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AT anilkumargn crystalstructureof44b8adihydro9hpyrido34bindol1yl7methyl2hchromen2one

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