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On the origin of the stereoselectivity in chiral amide-based ammonium ylide-mediated epoxidations
ABSTRACT: Detailed DFT studies provide an in-depth mechanistic understanding for the use of chiral amide-based ammonium ylides in epoxidation reactions. It is shown that the used chiral auxiliary efficiently shields one face of the ylide, which thus results in an extraordinarily high stereoselectivi...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Springer Vienna
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5225234/ https://www.ncbi.nlm.nih.gov/pubmed/28127093 http://dx.doi.org/10.1007/s00706-016-1866-8 |