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Sequential and iterative Pd-catalyzed cross-coupling reactions in organic synthesis

ABSTRACT: Sequential and iterative Pd-catalyzed cross-coupling reactions can be performed in which the order of C–C bond formations can be controlled either by the attenuated leaving groups of the multireactive substrate or by specific catalyst/ligand combinations. This tutorial review gives an over...

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Detalles Bibliográficos
Autores principales: Dobrounig, Patrick, Trobe, Melanie, Breinbauer, Rolf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5225241/
https://www.ncbi.nlm.nih.gov/pubmed/28127089
http://dx.doi.org/10.1007/s00706-016-1883-7
Descripción
Sumario:ABSTRACT: Sequential and iterative Pd-catalyzed cross-coupling reactions can be performed in which the order of C–C bond formations can be controlled either by the attenuated leaving groups of the multireactive substrate or by specific catalyst/ligand combinations. This tutorial review gives an overview about recent developments in this field and the various strategies used for the assembly of oligoarenes and -alkenes. GRAPHICAL ABSTRACT: [Image: see text]