Mechanism, reactivity, and regioselectivity in rhodium-catalyzed asymmetric ring-opening reactions of oxabicyclic alkenes: a DFT Investigation

The origin of the enantio- and regioselectivity of ring-opening reaction of oxabicyclic alkenes catalyzed by rhodium/Josiphos has been examined using M06-2X density functional theory(DFT). DFT calculations predict a 98% ee for the enantioselectivity and only the 1,2-trans product as one regio- and d...

Descripción completa

Detalles Bibliográficos
Autores principales: Qi, Zheng-Hang, Zhang, Yi, Gao, Yun, Zhang, Ye, Wang, Xing-Wang, Wang, Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5225450/
https://www.ncbi.nlm.nih.gov/pubmed/28074930
http://dx.doi.org/10.1038/srep40491

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5225450/
https://www.ncbi.nlm.nih.gov/pubmed/28074930
http://dx.doi.org/10.1038/srep40491

Ejemplares similares