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New experimental evidence to support roaming in the reaction Cl + isobutene (i-C(4)H(8))

The reaction Cl + isobutene (i-C(4)H(8)) was reported by Suits et al. to proceed via, in addition to abstraction, an addition-elimination path following a roaming excursion of Cl; a near-zero translational energy release and an isotropic angular distribution observed at a small collision energy char...

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Detalles Bibliográficos
Autores principales: Chen, Li-Wei, Hung, Ching-Ming, Matsui, Hiroyuki, Lee, Yuan-Pern
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5228202/
https://www.ncbi.nlm.nih.gov/pubmed/28079173
http://dx.doi.org/10.1038/srep40105