Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction

Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol–yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal sta...

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Detalles Bibliográficos
Autores principales: Lang, Mathias, Schade, Alexandra, Bräse, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238528/
https://www.ncbi.nlm.nih.gov/pubmed/28144326
http://dx.doi.org/10.3762/bjoc.12.252
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author Lang, Mathias
Schade, Alexandra
Bräse, Stefan
author_facet Lang, Mathias
Schade, Alexandra
Bräse, Stefan
author_sort Lang, Mathias
collection PubMed
description Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol–yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.
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spelling pubmed-52385282017-01-31 Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction Lang, Mathias Schade, Alexandra Bräse, Stefan Beilstein J Org Chem Full Research Paper Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol–yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents. Beilstein-Institut 2016-11-29 /pmc/articles/PMC5238528/ /pubmed/28144326 http://dx.doi.org/10.3762/bjoc.12.252 Text en Copyright © 2016, Lang et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Lang, Mathias
Schade, Alexandra
Bräse, Stefan
Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction
title Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction
title_full Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction
title_fullStr Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction
title_full_unstemmed Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction
title_short Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction
title_sort synthesis of three-dimensional porous hyper-crosslinked polymers via thiol–yne reaction
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238528/
https://www.ncbi.nlm.nih.gov/pubmed/28144326
http://dx.doi.org/10.3762/bjoc.12.252
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