Formose reaction accelerated in aerosol-OT reverse micelles

The formose reaction in reverse micelles of aerosol-OT (AOT), triton X-100 (TX), and hexadecyltrimethylammonium bromide (CTAB) was investigated. Time–conversion data have indicated that the interfacial water layer of AOT reverse micelles is a medium that accelerates formation of glycolaldehyde in th...

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Detalles Bibliográficos
Autores principales: Masaoka, Makoto, Michitaka, Tomohiro, Hashidzume, Akihito
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238542/
https://www.ncbi.nlm.nih.gov/pubmed/28144336
http://dx.doi.org/10.3762/bjoc.12.262
Descripción
Sumario:The formose reaction in reverse micelles of aerosol-OT (AOT), triton X-100 (TX), and hexadecyltrimethylammonium bromide (CTAB) was investigated. Time–conversion data have indicated that the interfacial water layer of AOT reverse micelles is a medium that accelerates formation of glycolaldehyde in the formose reaction. The (13)C NMR spectra for the products of the formose reaction using formaldehyde-(13)C as starting material are indicative of the formation of ethylene glycol as a major product.

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